nitration of phenol and various 4-substituted phenols with cu(no3)2.3h2o, cu(no3)2.3h2o/sio2, 9h2o and cr(no3)2. 9h2o in different anhydrous organic solvents are investigated. high selectivity ratio of para vs ortho isomers has been observed. mono- and dinitro compounds from phenol and 4-substituted phenols by choosing the proper solvents and reaction conditions, are also obtained with high sel...

The series: 9-methyl, 9-isopropyl, 9-cyclohexyl, 9,9-dimethyl, 9,9-diethyl, and the unsubstituted parent 2,7-bis (acetamido) fluorene were synthesized from the corresponding 9-substituted fluorenes. The two routes employed consisted of either (1) dinitration, reduction to the diamine, and diacetylation, or (2) Friedel-Crafts diacylation, then rearrangement via the Schmidt reaction. This provide...

The series: 9-methyl, 9-isopropyl, 9-cyclohexyl, 9,9-dimethyl, 9,9-diethyl, and the unsubstituted parent 2,7-bis (acetamido) fluorene were synthesized from the corresponding 9-substituted fluorenes. The two routes employed consisted of either (1) dinitration, reduction to the diamine, and diacetylation, or (2) Friedel-Crafts diacylation, then rearrangement via the Schmidt reaction. This provide...

5,12-Dihydroindolo[3,2-a]carbazole is a promising scaffold for the design of visible light photoinitiators polymerization due to simultaneous presence two carbazole moieties that can be differently functionalized. Notably, redshift absorption spectra facilely obtained by nitration one carbazoles, second group being functionalized with various groups. Dinitration 5,12-dihydroindolo[3,2-a]carbazo...

Nitration of phenol and various 4-substituted phenols with Cu(NO3)2.3H2O, Cu(NO3)2.3H2O/SiO2, 9H2O and Cr(NO3)2. 9H2O in different anhydrous organic solvents are investigated. High selectivity ratio of para vs ortho isomers has been observed. Mono- and dinitro compounds f...

Dibromination of [2.2]paracyclophane (I) led to predominantly pseudo-ortho2 (11) and pseudo-para2 (111) disubstituted compounds, and to lesser amounts of pseudo-meta (IV) and para (V) isomers. Oxidation of these dibromides gave terephthalic acids whose esters were identified by vpc, and whose structures allowed homoannular and transannular bromination to be differentiated. Tetrabromination of I...