The dilute bismide semiconductor GaAs1-xBix represents an interesting counterpart of the dilute nitride alloy GaAs1-xNx. Both exhibit giant bandgap bowing phenomena but with oppositely directed effects on the valence and conduction bands respectively. The optical properties of the dilute bismide alloy will be contrasted with those of the dilute nitride and the similarities and distinctions betw...

The band structures of dilute-As AlNAs alloys with As composition ranging from 0% up to 12.5% are studied by using First-Principle Density Functional Theory (DFT) calculation. The energy band gap shows remarkable reduction from 6.19 eV to 3.87 eV with small amount of As content in the AlNAs alloy, which covers the deep ultraviolet (UV) spectral regime. A giant bowing parameter of 30.5 eV ± 0.5 ...

The problems involved in calculating correlation factors for diffusion in dilute alloys can be contrasted to those arising in concentrated solid solutions. As one moves from the pure element to the dilute alloy to the concentrated alloy, the calculation becomes progressively more difficult. Because of the complex atom configurations which can occur in concentrated alloys, it usually is not poss...

We study states in the superconducting gap induced by magnetic impurities using self-consistent quantum Monte Carlo with maximum entropy and formally exact analytic continuation methods. The magnetic impurity susceptibility has different characteristics for T0 & Tc0 and T0 * Tc0 (T0: Kondo temperature; Tc0: superconducting transition temperature) due to the crossover between a doublet and a sin...

The electrochemical and corrosion behavior of a stainless-steel-based alloy made as a prototype metallic nuclear wasteform to immobilize Tc, has been studied in a number of reference solutions ranging in pH from 4 to 10. The results showed the 47SS(304)-9Zr–23Mo prototype alloy contained at least five distinct phases with the majority of the Re, used as a Tc surrogate, contained within a Fe2Mo ...

Using low-energy electron microscopy, we measure the diffusion of Pd into bulk Cu at the Cu(100) surface. Interdiffusion is tracked by measuring the dissolution of the Cu(100)-c(2 × 2)-Pd surface alloy during annealing (T>240 °C). The activation barrier for Pd diffusion from the surface alloy into the bulk is determined to be (1.8 ± 0.6) eV. During annealing, we observe the growth of a new laye...

A fully relativistic description of the spin-orbit induced spin Hall effect is presented that is based on Kubo's linear response formalism. Using an appropriate operator for the spin-current density a Kubo-Středa-like equation for the spin Hall conductivity (SHC) is obtained. An implementation using the Korringa-Kohn-Rostoker band structure method in combination with the coherent potential appr...