in present study we determine the zinc and lead levels in human blood samples by differential pulse polarography under optimum experimental conditions (ph=7.5, scan rate=5mv/s and pulse amplitude=50mv) the polarographic reduction peaks of zn and pb were examinedin the -0.72 v and-0.15 respectively. the zinc and lead content can be determined by in comparison with their standard solutions. accor...

Multi-walled carbon nanotubes (MWCNTs) were immobilized on the surface of a glassy carbon electrode (GCE) in the presence of cetyltrimethylammonium bromide (CTAB) to form a MWCNTs-CTAB nanocomposite-modified electrode. The electrocatalytic response of the modified electrode towards tryptophan (Trp) was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The surface...

the voltammetric characteristics of mo (vi) oxinate at the mercury electrode, in the presence of tri-butylammonium perchlorate (tri-bap) and piperidinium perchlorate (pp) + piperidine (p) as  two different types supporting electrolytes, have been studied in chloroform. with the both supporting electrolytes a two electron irreversible process for the reduction  of mo (vi) oxinate was observed. p...

lead forms the complexes with xylenol orange in the basic solution. an adsorptivedifferential pulse stripping method for the determination of lead is proposed. the procedureinvolves an adsorptive accumulation of lead on a hanging mercury drop electrode (hmde) inthe presence of xylenol orange, followed by reduction of adsorbed lead by voltammetric scanusing differential pulse modulation. the opt...

furan is a possible human carcinogen in many types of foods. a new and sensitive electroanalytical method for determination of furan has been developed and validated. the best condition forelectrochemical response was obtained with 0.1 m britton-rabinson buffer solution (ph=5) a glassy carbonelectrode (gce) was used as the working electrode, a ag/agcl/ kcl(sat.) electrode served as the referenc...

in this paper, we introduce hybrid of block-pulse functions and bernstein polynomials and derive operational matrices of integration, dual, differentiation, product and delay of these hybrid functions by a general procedure that can be used for other polynomials or orthogonal functions. then, we utilize them to solvedelay differential equations and time-delay system. the method is based upon ex...

in this study, simple, fast and reliable cyclic voltammetry (cv), linear sweep voltammetry (lsv), square wave voltammetry (swv) and differential pulse voltammetry (dpv) methods were developed and validated for determination of bosentan in pharmaceutical preparations. the proposed methods were based on electrochemical oxidation of bosentan at platinum electrode in acetonitrile solution containin...

in this paper, an effective numerical method is introduced for the treatment of nonlinear two-dimensional volterra-fredholm integro-differential equations. here, we use the so-called two-dimensional block-pulse functions.first, the two-dimensional block-pulse operational matrix of integration and differentiation has been presented. then, by using this matrices, the nonlinear two-dimensional vol...

In this paper, an effective numerical method is introduced for the treatment of nonlinear two-dimensional Volterra-Fredholm integro-differential equations. Here, we use the so-called two-dimensional block-pulse functions.First, the two-dimensional block-pulse operational matrix of integration and differentiation has been presented. Then, by using this matrices, the nonlinear two-dimensional Vol...

furan is a possible human carcinogen in many types of foods. a new and sensitive electroanalytical method for determination of furan has been developed and validated. the best condition forelectrochemical response was obtained with 0.1 m britton-rabinson buffer solution (ph=5) a glassy carbonelectrode (gce) was used as the working electrode, a ag/agcl/ kcl(sat.) electrode served as the referenc...