a series of new heteroleptic chelated copper(ii) complexes that encompass n,n-dibezyl substituted derivative of ethylenediamine (x-diamine) and acetylacetonate (acac) were prepared.  the ir and electronic absorption spectra and the molar conductivity of the complexes are presented and discussed.  the molar conductivity values of the complexes in different solvents reveals a predominance of elec...

The infrared and electronic absorption spectra of a series of new heteroleptic chelated copper (II) complexes [Cu(diamine)(acac)]X that encompass N,N'-1,6-bis(2-bromophenyl)-2,5-diazahexane (diamine), acetylacetonate (acac) and ClO , BPh , PF and BF (X) were studied. The IR, electronic absorption spectra and 4 4 6 4 the molar conductivity of the newly prepared complexes were presented and discu...

A series of new heteroleptic chelated copper(II) complexes that encompass N,N-dibezyl substituted derivative of ethylenediamine (X-diamine) and acetylacetonate (acac) were prepared.  The IR and electronic absorption spectra and the molar conductivity of the complexes are presented and discussed.  The molar conductivity values of the complexes in different solvents reveals a predominance of elec...

The very sensitive, fairly selective direct spectrophotometric method for the determination of trace amount of vanadium (V) with naphthalene -1, 5 -diamine has been developed. Naphthalene -1, 5 -diamine reacts in slightly acidic (0.0001– 0.001 M H2SO4 or pH 4.0–5.5) alcohol media with vanadium (V) to give a red–violet chelate which has an absorption maximum at 531 nm. The stoichiometric composi...

In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa-hedral environment, coordinated by four N atoms of the 4,7-diaza-decane-1,10-diamine ligand, one water mol-ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structur...

The lipophilicity of a series of Schiff base ligands and their complexes with nickel(II) and copper(II) has been determined by reversed-phase thin-layer chromatography using binary dioxane-water mobile phase. Chelate ligands were prepared by condensation of diamine and the corresponding beta-diketone. Copper(II) and nickel(II) complexes with chelate ligands containing ethane-1,2-diamine or prop...

Substitution of an acetylacetonate by a carboxylate in the neutral (acac)2Cu(II) was achieved by its reaction with triand dichloroacetic acid in benzene (HCO2R where R = CCI3 or CHCI2; Hacac = acetylacetone) which led to the formation of the mixed chelate square planar complex (acac)Cu(OCOR). The later complex, R = CCI3, reacted with heterocyclic bases to produce the square pyramidal complexes ...

The synthesis of the new potentially hexadentate ligands N,N'-bis(2,2'-bipyridin-6-ylmethyl)butane-1,4-diamine (bmbu), N,N'-bis(2,2'-bipyridin-6-ylmethyl)pentane-1,5-diamine (bmpt) and N,N'-bis(2,2'-bipyridin-6-ylmethyl)octane-1,8-diamine (bmot) from the condensation of 2,2'-bipyridine-6-carbaldehyde with the appropriate diamine (butane-1,4-diamine, pentane-1,5-diamine and octane-1,8-diamine, r...

Results on the autooxidative decomposition of the transition metal B-diketonates (1-3) suggested the possibility of these chelates acting as initiators for the radical polymerization of vinyl monomers. Research in this field soon revealed the importance of the central metal atom as well as the ligand structure (4-10). Of a series of metal acetylacetonate~-Mn(Acac)~, M n ( A ~ a c ) ~ , Fe( A ~ ...

the kinetics of the de complexation by hydroxyl ions of some pervanadyl, molybdate and tungstate amionocarboxylate complexes have been studied spectrophotometrically by means of a stopped flow technique. the chelate groups used were the iminodiacetic acid (ida), ethylenediarnine-n,n' -diacetic acid (edda), nitrilotriacetic acid (nta) and ethylene diamine-n,n,n' ,n'-tetraacetic ac...