several novel mononuclear zn(ii) complexes, [zn(bpy)l2], where bpy=2,2’-bipyridine and l=monoanions of phenylcyanamide (pcyd), 4-methylphenylcyanamide (4-mepcyd), 3,5-dimethylphenylcyanamide(3,5-me2pcyd),4-methoxyphenylcyanamide(4-meopcyd), 3,5-dimeth-oxyphenylcyanamide (3,5-meo2pcyd), 3-chlorophenylcyanamide (3-clpcyd), 2,3-dichlorophenyl-cyanamide (2,3-cl2pcyd), 4-bromophenylcyanamide (4-brpc...

Electrodes based on carbon, i.e., expanded graphite (20%, wt.)-epoxy composite(20EG-Epoxy) and expanded graphite (20%, wt.)-polystyrene composite (20EG-PS) havebeen prepared, characterized using scanning electron microscopy (SEM) and cyclicvoltammetry (CV), and tested as anodic sensors. The electrodes exhibited good mechanicalresistance and low electrical resistances. Scan rate dependent cyclic...

In this contribution we describe the formation of gold nanoparticles (AuNP)and polyaniline (PANI) AuNP-PANI nanocomposite via in situ enzymaticpolymerization. The method consists electrostatic adsorption aniliniummonomers on AuNPs citrate stabilized surface 50 nm diameters, followedby oxidation with horseradish peroxidase (HRP) enzyme and its cofactorH2O2. All reaction steps were monitored by U...

in this work, a novel electrochemical technique is presented for determination of bentazonusing a nanocomposite based sensor and continuous coulometric fast fourier transformation cyclicvoltammetry (ccfftcv). in this method, the sensor response is in coulomb and is calculated based onintegrating charge changes under the current voltammogram in selected potential range. the new sensor wasconstru...

Several novel mononuclear Zn(II) complexes, [Zn(bpy)L2], where bpy=2,2’-bipyridine and L=monoanions of phenylcyanamide (pcyd), 4-methylphenylcyanamide (4-Mepcyd), 3,5-dimethylphenylcyanamide(3,5-Me2pcyd),4-methoxyphenylcyanamide(4-MeOpcyd), 3,5-dimeth-oxyphenylcyanamide (3,5-MeO2pcyd), 3-chlorophenylcyanamide (3-Clpcyd), 2,3-dichlo...