نتایج جستجو برای: cu zno
تعداد نتایج: 80474 فیلتر نتایج به سال:
Monolayer Cu₂S and ZnO, and three kinds of complex films, Cu₂S/ZnO, ZnO/Cu₂S, and ZnO/Cu₂S/ZnO, were deposited on glass substrates by means of radio frequency (RF) magnetron sputtering device. The impact of the thickness of ZnO and Cu₂S on the whole transmittance, conductivity, and photocatalysis was investigated. The optical and electrical properties of the multilayer were studied by optical s...
Stearate@Cu/ZnO nanocomposite particles with molar ratios of ZnO : Cu = 2 and 5 are synthesized by reduction of the metal–organic Cu precursor [Cu{(OCH(CH3)CH2N(CH3)2)}2] in the presence of stearate@ZnO nanoparticles. In the case of ZnO : Cu = 5, high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) combined with electronenergy-loss-spectroscopy (EELS) as well as ...
Stearate@Cu/ZnO nanocomposite particles with molar ratios of ZnO ∶ Cu = 2 and 5 are synthesized by reduction of the metal-organic Cu precursor [Cu{(OCH(CH(3))CH(2)N(CH(3))(2))}(2)] in the presence of stearate@ZnO nanoparticles. In the case of ZnO ∶ Cu = 5, high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) combined with electron-energy-loss-spectroscopy (EELS) ...
An environmentally benign antisolvent method has been developed to prepare Cu(2+)-doped ZnO nanocrystals with controllable dopant concentrations. A room temperature ionic liquid, known as a deep eutectic solvent (DES), was used as the solvent to dissolve ZnO powders. Upon the introduction of the ZnO-containing DES into a bad solvent which shows no solvation to ZnO, ZnO was precipitated and grow...
Nanoscale copper was selectively photodeposited onto the surface of hexadecylamine (HDA) stabilized (monodispersed not agglomerated) ZnO nanoparticles (NPs) of a diameter of 2-5 nm, which leads to HDA-stabilized Cu/ZnO NPs of varied Cu loading. The particles are soluble in non-polar organic solvents. The line broadening and the red shift of the surface plasmon band of Cu/ZnO NPs relative to HDA...
Microstructural characteristics of various real Cu/ZnO/Al2O3 catalysts for methanol steam reforming (MSR) were investigated by in situ X-ray diffraction (XRD), in situ X-ray absorption spectroscopy (XAS), temperature programmed reduction (TPR) and electron microscopy (TEM). Structure–activity correlations of binary Cu/ZnO model catalysts were compared to microstructural properties of the ternar...
A combined experimental and first principles study of Cu defects in bulk ZnO is presented. Cu particles are epitaxially deposited on the polar O-ZnO(0001) surface at room temperature. Upon heating, a broadening of the quasielastic peak in high resolution electron energy loss spectra is observed, corresponding to an electronic doping effect of Cu atoms in bulk ZnO with an ionization energy of 88...
Copper-based catalysts are industrially applied in various reactions including water-gas shift, synthesis of fatty alcohols from fatty acid methyl esters, and methanol synthesis. Today, methanol is produced at low pressures (35-55 bar) and 200-300°C over Cu/ZnO/Al2O3 catalysts. Due to the great commercial relevance, Cu/ZnO-based catalysts have been extensively studied and many different models ...
Bi-phase dispersible Cu-ZnO hybrid nanoparticles were synthesized by one-pot non-aqueous nanoemulsion with the use of poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) (PEO-PPO-PEO) as the surfactant. The transmission electron microscopy (TEM) and X-ray diffraction (XRD) show high crystallinity of the Cu-ZnO hybrid nanoparticles and an average particle size of ~19.4...
Multi-walled carbon nanotubes (MWNTs)/Cu-doped ZnO composite powders were prepared by co-precipitation method, and were characterized by X-ray diffraction, electron microscopy, fluorescence spectrum, and ultraviolet spectrum. Experimental results show that the MWNTs can be modified by Cu-doped ZnO nanoparticles with hexagonal wurtzite structure after annealed at 450 °C, and the nanoparticle siz...
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