single-walled carbon nanotubes (swcnt) and multi-walled carbon nanotubes(mwcnt) were melt-blended with polyvinylidene fluoride (pvdf).ft-ir technique revealed that swcnt has insignificant effect on the crystalline structure of pvdf and at 3wt% modification only 14% beta crystal isformed. this observation was accounted for by the chair structure of swcnt. in mwcnt nancomposites it was found that...

Using transition path sampling computer simulations, we reveal the nucleation mechanism of a pressure-induced structural transformation in CdSe nanocrystals. Consistent with experiments, the thermodynamic transition pressure of the transformation increases with decreasing crystal size. Through transition state analysis, we identify the critical nuclei and characterize them by calculating activa...

A single-crystal to single-crystal (SC-SC) transformation process driven by water molecules has been exhibited by a multi-metallic coordination polymer. The in situ heating single crystal X-ray diffraction technique was applied to study the control of metal ion movement in the reversible SC-SC transformation process.

Formation of stray grain defects particularly around re-entrant features of the turbine blade airfoils is one of the major problems in directional and single crystal solidification processes. In this work, directional solidification tests of the GTD-111 Ni-based superalloy were conducted at different withdrawal velocities of 3, 6 and 9 mm.min-1 using various stepped cylindrical and cubic design...

A mechanism for crystal-crystal phase transformations (PTs) via surface-induced virtual premelting is justified thermodynamically and confirmed experimentally for the PTs in PbTiO3 nanofibers. When the thickness of the surface melt (which appears much below the melting temperature, especially for nanoobjects) exceeds the size of the critical product nucleus, nucleation and growth of the product...

Reversible single-crystal-to-single-crystal transformation (SCSC) was for the first time observed between 4f-based molecular magnets.

We study adiabatic transformation in optical waveguides with discrete translational symmetry. We calculate the reflection and transmission coefficient for a structure consisting of a slab waveguide that is adiabatically transformed into a photonic crystal waveguide and then back into a slab waveguide. The calculation yields high transmission over a wide frequency range of the photonic crystal w...