In this study for the first time a new description of compressibility factor is rendered based on the virial expansion. The compressibility factor as a function of M-factor is qualitatively and quantitatively expressed. At first, we present how may the third, fourth and higher order virial coefficients be logically ignored in order to simplify the virial equation. The results show, wh...

The compressibility factor of nonassociated chain molecules composed of hard convex core Yukawa segments was derived with SAFT-VR and an extension of the Barker-Henderson perturbation theory for convex bodies. The temperature-dependent chain and dispersion compressibility factors were derived using the Yukawa potential. The effects of temperature, packing fraction, and segment number on the com...

in this study for the first time a new description of compressibility factor is rendered based on the virial expansion. the compressibility factor as a function of m-factor is qualitatively and quantitatively expressed. at first, we present how may the third, fourth and higher order virial coefficients be logically ignored in order to simplify the virial equation. the results show, when the com...

the compressibility factor of nonassociated chain molecules composed of hard convex core yukawa segments was derived with saft-vr and an extension of the barker-henderson perturbation theory for convex bodies. the temperature-dependent chain and dispersion compressibility factors were derived using the yukawa potential. the effects of temperature, packing fraction, and segment number on the com...

Analytic expressions were derived for the compressibility factor and residual internal energy of the square-well plus Sutherland fluid. In this derivation, we used the second order Barker-Henderson perturbation theory based on the macroscopic compressibility approximation together with an analytical expression for radial distribution function of the reference hard sphere fluid. These properties...

compressibility factor and viscosity of natural gasses are of great importance in petroleum and chemical engineering. to calculate the natural gas properties in the pipelines, storage systems and reservoirs, the exact values of gas compressibility factor and viscosity are required. a new method that allows accurate determination of compressibility factor and gas viscosity for all types of: swee...

Compressibility factor and viscosity of natural gasses are of great importance in petroleum and chemical engineering. To calculate the natural gas properties in the pipelines, storage systems and reservoirs, the exact values of gas compressibility factor and viscosity are required. A new method that allows accurate determination of compressibility factor and gas viscosity for all types of: swee...

gas compressibility factor (z-factor) is an important parameter widely applied in petroleum and chemical engineering. experimental measurements, equations of state (eoss) and empirical correlations are the most common sources in z-factor calculations. however, these methods have serious limitations such as being time-consuming as well as those from a computational point of view, like instabilit...

based on the carnahan and starling hard sphere equation of compressibility, an equation of state has been derived. conditions that must be met by all equations of state are applied in order to obtain attractive term or non - ideal compressibility term of the equation. second virial coefficient and acentric factor arc used in the derivation of the equation of state. in this equation, compressibi...

Gas compressibility factor (z-factor) is an important parameter widely applied in petroleum and chemical engineering. Experimental measurements, equations of state (EOSs) and empirical correlations are the most common sources in z-factor calculations. However, these methods have serious limitations such as being time-consuming as well as those from a computational point of view, like instabilit...