Porous surface modified polyvinylidene ï‌‚uoride (PVDF) hollow fiber membranes are fabricated through a dry-wet phased inversion process. Surface modifying macromolecules (SMM) (1 wt. %) are used as additives in the spinning dope. The performance of the surface modified membrane in contactor application for CO2 stripping from water is assessed through the fabricated gas–liquid membrane contacto...

in this research, process asymmetric polyetherimide hollow fiber membranes using ethanol (0, 2 and 4 wt%) as non-solvent additive in the polymer dope via phase inversion method were fabricated. aqueous solution of 1-methyl-2-pyrrolidine (nmp) (90%) was applied as a bore fluid to avoid inner skin layer formation and water was used as the external coagulant. the morphology of fabricated membranes...

Mononethanolamine (MEA)-based absorption-stripping for CO2 capture is studied. Energy demands in this process are dominated by the stripping column. The shortest stripping line distance approach is used to determine minimum energy requirements for the MEA stripping column under various lean loadings. Simultaneous reaction and vapor-liquid equilibrium is assumed and modeled by the direct incorpo...

Project Goals: We are developing Bacillus megaterium as a host for continuous biofuel production coupled with in situ product extraction by supercritical CO2 (scCO2) stripping. We employ a cross-disciplinary collaborative approach to achieve the following: (1) Develop a supercritical CO2 tolerant strain of B. megaterium into a bioproduction host for biofuels (2) Engineer de novo pathways for bi...

In this paper we report some experimental results concerning the stripping in any portion of the optical fibers at 10.6 μm wavelength. These experimental procedures have been performed using a CO2 laser with 40 W power and a galvanometer scanner with 150 mm focal length. The objective of this paper was to find the optimal conditions (speed of the laser along the optical fiber) for a good stripp...

Monoethanolamine (MEA) scrubbing is an energy-intensive process for carbon capture and sequestration (CCS) due to the regeneration of amine in stripping towers at high temperature (100–120°C) and the subsequent pressurization of CO2 for geological sequestration. In this paper, we introduce a novel method, reactive hydrothermal liquid phase densification (rHLPD), which is able to solidify (densi...

In this work, the chemical and thermal stability of a primary amine-functionalized ion-exchange resin (Lewatit VP OC 1065) is studied in view of the potential options of regenerating this sorbent in a CO2 removal application. The adsorbent was treated continuously in the presence of air, different O2/CO2/N2 mixtures, concentrated CO2, and steam, and then the remaining CO2 adsorption capacity wa...

Increasing atmospheric levels of CO2, in large part due to anthropogenic combustion of energy yielding hydrocarbons, portends significant if not catastrophic weather related events. One strategy to stabilize atmospheric CO2 levels is to capture the post-combustion product for disposal or, preferably, commercial use. The latter case, in particular, requires the development of both effective and ...

In this study, plantwide control of an absorption/stripping CO2 capture process using mono-ethanol-amine was investigated using dynamic simulation. In this system, CO2 removal ratio is influenced by operating variables such as lean solvent rate and lean solvent loading, which is in-turn determined by reboiler duty in the stripper. Moreover, we found that the long term stability of the system ca...

MIL-101(Cr) has drawn much attention due to its high stability compared with other metal-organic frameworks. In this study, three trace flue gas contaminants (H2O, NO, SO2) were each added to a 10 vol% CO2/N2 feed flow and found to have a minimal impact on the adsorption capacity of CO2. In dynamic CO2 regeneration experiments, complete regeneration occurred in 10 min at 328 K for temperature s...