silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. it also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol

the treatment equimolar quantities of carboxylic acids with acid chlorides in the presence of zno brings abouthighly efficient unsymmetrical anhydrides at room temperature in solvent-free condition. reactivity trendsfavored formation of the product using both electron deficient and rich aryl acids and acid chlorides.

Silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. It also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol

Introduction: Chlorides and perchlorates present on Mars can form aqueous solutions because of low temperature eutectics and related lower evaporation rates [1]. The recent discovery of chlorides and perchlorates on Mars by NASA’s Phoenix Lander [2] reinforced the potential for chlorides on Mars. Chlorides present in databases lack spectral features (absorption bands) in the near-infrared. Most...

1. A method is given for determining the chloride content in a drop (less than 0.03 cc.) of the cell sap of Nitella. 2. Chlorides accumulate in the sap to the extent of 0.128 M; this accumulation can be followed during the growth of the cell. The chloride content does not increase when the cell is placed for 2 days in solutions (at pH 6.2) containing chlorides up to 0.128 M. 3. The exosmosis of...

The KF, sucrose (table sugar) exploited as quenching system in solution phase parallel synthesis. Excess of electrophiles were covalently trapped with hydroxyl functionality of sucrose and due to polar nature of sucrose derivative was solubilize in water. Potassium fluoride used to convert various excess electrophilic reagents such as acid chlorides, sulfonyl chlorides, isocyanates to correspon...

A series of bulky geometry-constrained iminopyridylpalladium chlorides were developed. The steric environment adjacent to the nitrogen atom in the pyridine rings and diimine parts enhanced the thermal stability of the palladium species. Bulkier groups at the imino group stabilized the palladium species and the corresponding palladium chlorides showed high activities in the coupling reaction of ...

Dogs injected with proteose recovered from the intestinal contents of animals with obstruction at different levels show no significant changes in the blood chlorides even with a fatal intoxication. After the intravenous injection of lethal and sublethal doses of Witte's peptone there is little change in the chlorides. Autolyzing liver in the abdominal cavity produces no change in the blood chlo...

Sodium bentonite was subjected to the effect of two new homologue series of chlorides (alcoxymethyl) dimethyloctyloamonium chlorides and 3-alcoxymethyl-1-octylimidazole chlorides with the hydrophobic substituents of the same length. Morphology of the obtained modified bentonite was studied under scanning electron microscope [SEM] and the degree of adsorption of the ammonium salts was determined...

Phosphanyl-beta-ketoiminate Pd complexes serve as highly effective catalysts in the Stille coupling reaction of aryl chlorides and heteroaryl chlorides with organostannanes at room temperature.