24-hour samples of pm1 (submicron particles, aerodynamic diameters ≤1 μm) and pm2.5(fine particles, aerodynamic diameters ≤ 2.5 μm) were collected at a quasi-rural area in racibórz (1 january-30 june 2011). the samples were analysed for carbon (organic and elemental), water-soluble ions (na+,nh4 +, k+, mg2+, ca2+, cl-, no3 -, so4 2-) and concentrations of 21 elements with a carbon analyser (sun...

The aerosol chemical mass closure is revisited and a simple and inexpensive methodology is proposed. This methodology relies on data obtained for aerosol mass, and concentration of the major ions and the two main carbon components, the organic carbon (OC) and the black carbon (BC). Atmospheric particles are separated into coarse 5 (AD>2 µm) and fine (AD<2 µm) fractions and are treated separatel...

The chemical characteristics of ambient particulate matters in urban and rural areas of Hong Kong were determined in this study. A monitoring program starting from November 2000 to February 2001 (winter) and June 2001 to August 2001 (summer) for PM10 and PM2.5 was performed at three monitoring stations in Hong Kong. Twenty-four-hour PM10 and PM2.5 samples were collected once every 6 days at two...

Aerosol mass closure and reconstruction of the light scattering coefficient over the Eastern Mediterranean Sea during the MINOS campaign J. Sciare, K. Oikonomou, H. Cachier, N. Mihalopoulos, M. O. Andreae, W. Maenhaut, and R. Sarda-Estève Department of Biogeochemistry, Max Planck Institute for Chemistry, Mainz, Germany Department of Chemistry, University of Crete (ECPL), Heraklion, Crete, Greec...

The upscaling process of mass transport with chemical reaction in porous media is carried out using the method of volume averaging under diffusive and dispersive conditions. We study cases in which the (first-order) reaction takes place in the fluid phase that saturates the porous medium or when the reaction occurs at the solid-fluid interface. The upscaling effort leads to average transport eq...

Philosophers have long debated ‘substrate’ and ‘bundle’ theories as to how properties hold together in objects ― but have neglected to consider that every chemical entity is defined by closure of relationships among components ― here designated ‘Closure Louis de Broglie.’ That type of closure underlies the coherence of spectroscopic and chemical properties of chemical substances, and is importa...