Atmospheric carbonyls were measured at a semi-urban site in Orléans, France, from October 2010 to July 2011. Formaldehyde, acetaldehyde and acetone were found to be the most abundant carbonyls, with average concentrations of 3.1, 1.0, 2.0 ppb, respectively in summer, 2.3, 0.7, 2.2 ppb, respectively in autumn, 2.2, 1.0, 2.1 ppb, respectively in spring, and 1.5, 0.7, 1.1 ppb, respectively in wint...

two continuously regenerating traps crt-a and crt-b were evaluated under the controlled carbonyl emissions from a turbocharged diesel engine run on an ac electrical dynamometer. the gas-phase carbonyls were taken in silica gel cartridges coated with 2,4-dinitrophenylhydrazine both upstream (baseline) and downstream of the traps, and a total of fourteen carbonyls were identified and then quantif...

Characteristics of carbonyl compounds (carbonyls) emissions from biodiesel–ethanol–diesel (BE–diesel) were investigated in a Commins-4B diesel engine and compared with those from fossil diesel. Acetaldehyde was the most abundant carbonyls in the exhaust, followed by formaldehyde, acetone, propionaldehyde and benzaldehyde. Apliphatic carbonyls emitted from BE–diesel were higher than those from d...

protein oxidationm.longissimus dorsi andm. semimembranosuswas studied in ram lambs of northeastern bulgarian fine wool breed and cross of this breed with ile de france, reared and in doors and on pasture.the degree of protein oxidation is determined by measuring the content of carbonyls, formed during the storage of the investigated muscles at low temperatures(4˚с till6thday and -20˚с till90thd...

Emissions of carbonyls by motor vehicles are of concern because these species can be hazardous to human health and highly reactive in the atmosphere. The objective of this research was to measure carbonyl emission factors for California light-duty motor vehicles. Measurements were made at the entrance and exit of a San Francisco Bay area highway tunnel, in the center bore where heavy-duty truck...

Carbonyls from gasoline-powered light-duty vehicles (LDVs) and heavy-duty diesel-powered vehicles (HDDVs) operated on chassis dynamometers were measured by use of an annular denuder-quartz filter-polyurethane foam sampler with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine derivatization and chromatography-mass spectrometry analyses. Two internal standards were utilized based on carbonyl recovery...

A fast HPLC method for the analysis of DNPH derivatized carbonyls found in air samples is demonstrated. A 1.8-μm StableBond C18 separated a standard of the major 13 DNPH derivatized carbonyls. An air sample was analyzed in under 10 minutes and found to contain several carbonyls.

Liquid chromatography coupled with atmospheric pressure chemical ionization (APCI) ion trap mass spectrometry (ITMS) is applied to atmospheric aerosol relevant carbonyls. Characterization of positive and negative ion detection mass spectra are presented for 24 model compounds analyzed in their underivatized and O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) oxime forms. The addition of PF...