An analytical methodology based on spectrophotometric and partial least squares (PLS) algorithm for thesimultaneous determination of ampicillin and penicillin in human plasma was developed and validated. Themultivariate model was developed as a binary calibration model and it was built and validated with anindependent set of synthesis and real samples in presence of matrix. It is shown how a de...

This research reports a validated multi-residue method based on gas chromatography coupled mass spectrometry technique for analysis of 24 Polycyclic Aromatic Hydrocarbons (PAHs) in traditional and semi-industrial Taftoon bread using QuEChERS sample preparation. Matrix effect studies were performed by comparing the slopes of solvent based standard calibration curves and spiked calibration curves...

This research reports a validated multi-residue method based on gas chromatography coupled mass spectrometry technique for analysis of 24 Polycyclic Aromatic Hydrocarbons (PAHs) in traditional and semi-industrial Taftoon bread using QuEChERS sample preparation. Matrix effect studies were performed by comparing the slopes of solvent based standard calibration curves and spiked calibration curves...

By relating the projective camera model to the perspective one, the intrinsic camera parameters give rise to what is called the calibration matrix. This paper presents two new methods to retrieve the calibration matrix from the projective camera model. In both methods, a collective approach was adopted, using matrix representation. The calibration matrix was retrieved from a quadratic matrix te...

By relating the projective camera model to the perspective one, using homogenous coordinates representation, the interior orientation parameters constitute what is called the calibration matrix. This paper presents two new algorithms to retrieve the calibration matrix from the projective camera model. In both algorithms, a collective approach was adopted, using matrix factorization. The calibra...

The emergence of compressed sensing (CS) theory provides potential hardware architecture to sub-Nyquist sample the wideband signals. However, applying this discrete CS model to continuous analogue signals is not an easy task. The modulated wideband converter (MWC) is an efficient wideband compressed sampling architecture for the sparse multiband signals. In this paper, a soft-calibration system...

Free amino acids in plasma, muscle and liver tissues were determined using the Pico-Tag method which involves HPLC and pre-column derivatization. A study of the accuracy in the determination is carried out by means of external calibration, standard-added calibration, Youden calibration and analyte recovery. It is conclusively shown that the method is affected by a proportional systematic error ...

The influence of the sample matrix in the analysis of pesticides in vegetable samples has been studied in order to determine if the matrix content introduces a systematic or proportional (or both) bias in the measurements. Experiments have been carried out during a 4-month period, in which calibration curves, prepared in solvent and in vegetable matrix, were prepared and analysed. A statistical...

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