a novel complex of cadmium (ii) [cdl0.5(no3)(h2o)](1), l= n,n-bis (o-hydroxyacetophenone) ethylene diamine, have been synthesized as single crystal and nano size. compound 1 in nano size was obtained under sonochemical irradiation and has been characterized by ir, 1hnmr spectroscopy, x-ray powder diffraction (xrd) and scanning electron microscopy (sem). the gray single crystal of compound 1 has...

BACKGROUND The coordination chemistry of cadmium(II) with diamine ligands is of particular interest. The most common structure around cadmium(II) center in their complexes is tetrahedral, that is due the octet rule obeyed. Nevertheless, five and six-coordinated complexes are also well known. Now a day, many cadmium(II) complexes with chelate ligands were synthesized for their structural or appl...

The extraction and separation of copper(II), zinc(II), cobalt(II), and cadmium(II) were investigated. Both copper(II) and zinc(II) formed ammine-complexes, while cadmium(II) and cobalt(II) formed hydroxide precipitates in an ammonia medium. By the addition of sodium dodecylsulfate (SDS), a copper(II) complex formed an ion-pair (copper-ammine-DS), which was extracted into the SDS phase. However,...

Cadmium(II) complexes with thiolate ligands have received considerable attention because of their intriguing structural features and relevance to metalloproteins. In this study, a new cadmium(II)–rhodium(III) trinuclear complex, [Cd{Rh(apt)3}2]Br2·4H2O (1, apt = 3-aminopropanethiolate), was synthesized by the reaction fac-[Rh(apt)3] cadmium bromide. Compound 1 characterized using elemental anal...

a new tris-chelate cd(ii) complex, [cd(dadmbtz)3](clo3)2 has been successfully synthesized and characterized by ir, 1h, 13c nmr spectroscopy, elemental analysis and single crystal x-ray determination. the thermal behavior, uv-vis and fluorescence spectra of compound were studied. in reaction with dadmbtz, cadmium (ii) forms a tris-chelate complex with nearly c3 symmetry for coordination polyhed...

The Schiff bases (H3L), derived from 2-acetylpyrrole and carbonohydrazide, and its reactions with some transition metal ions (Co(II), Ni(II), Cu(II), Zn(II) and Cd(II)) afforded complexes of formulae [M(H5LA)2(H2O)x]∙2(NO3)∙(CH3CN)z∙(H2O)y-x (M= Co, Ni, Cu or Zn ; 0 ≤ x < y ≤ 3, z = 0 or 1) and {Cd(H4LA)(NO3)}n. These compounds have been characterized by means of elemental analysis, UV–Vis spec...

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...