direct orthogonal signal correction(dosc) and savitzky-golay filters (sgf) were applied as preprocessing methods on the original and first derivative absorbance data. principle component regression (pcr), partial least squares (pls) and iterative target transformation factor analysis (ittfa), were used in spectrophotometric simultaneous determination of heavy divalent metal ions, lead, zinc,mer...

a highly selective, rapid and economical differential pulse polarographic method has been developed for the determination of trace amounts of cadmium and lead present together in various standard alloys and biological samples after adsorption of their 1-(2-pyridylazo)-2-naphthol complexes on microcrystalline naphthalene. cadmium and lead complexes are equantitatively adsorbed on microcrystallin...

Determination of trace elements in food is of great importance, as some of them have nutritional significance, whilst others are toxic. Long-term exposure to low levels of toxic metals could be important, especially in relation to children. Differential Pulse Anodic Stripping Voltammetry (DPASV) is applied to simultaneous determination of lead, cadmium, copper and zinc in dry ash infant formula...

Determination of trace elements in food is of great importance, as some of them have nutritional significance, whilst others are toxic. Long-term exposure to low levels of toxic metals could be important, especially in relation to children. Differential Pulse Anodic Stripping Voltammetry (DPASV) is applied to simultaneous determination of lead, cadmium, copper and zinc in dry ash infant formula...

A highly selective, rapid and economical differential pulse polarographic method has been developed for the determination of trace amounts of cadmium and lead present together in various standard alloys and biological samples after adsorption of their 1-(2-pyridylazo)-2-naphthol complexes on microcrystalline naphthalene. Cadmium and lead complexes are equantitatively adsorbed on microcrysta...

a partial least squares (pls) calibration model was developed for the simultaneous spectrophotometricdetermination of pb (ιι), cu (ιι) and ni (ιι) using xylenol orange as a chromogenic reagent. the parameterscontrolling behavior of the system were investigated and optimum conditions were selected. the calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...

A new method for the simultaneous determination of lead, cadmium and mercury ions in microwave-digested foodstuffs by reversed-phase high-performance liquid chromatography combined with on-line enrichment technique has been developed. The foodstuff samples were digested by microwave digestion. The lead, cadmium and mercury ions can be precolumn derivatized with 5,10,15,20-tetrakis(3-aminophenyl...

determination of trace elements in food is of great importance, as some of them have nutritional significance, whilst others are toxic. long-term exposure to low levels of toxic metals could be important, especially in relation to children. differential pulse anodic stripping voltammetry (dpasv) is applied to simultaneous determination of lead, cadmium, copper and zinc in dry ash infant formula...