the aim of the present work is to prepare an adsorption package to simulate adsorption / desorption operation for both single and multi-component systems in an isothermal condition by different mechanisms such as; local adsorption theory and mass transfer resistance (rigorous and approximated methods). different mass transfer resistance mechanisms of pore, solid and bidispersed diffusion, toget...

the emerging contaminants are commonly derived from municipal, agricultural, and industrialwastewater sources and pathways. these compounds are polar and poorly biodegradable. the dynamicremoval of atenolol from aqueous solutions by activated carbon in fixed bed column systems was investigated. as far as we know, this is the first study reporting the decontamination by adsorption in fixed bed o...

We present an experimental and theoretical study of the breakthrough performance of the flexible metal-organic framework Cu(bpy)2(BF4)2 (bpy = 4,4'-bipyridine), termed ELM-11. Pure CO2, He, CH4, and N2 gases, as well as binary gas mixtures of those species, were used to perform breakthrough experiments on ELM-11. ELM-11 exhibits a stepped breakthrough curve for CO2 not seen in rigid adsorbents....

Removal of Fe (II) from aqueous media was investigated using chitosan as the adsorbent in both batch and continuous systems. Batch experiments were carried out at initial concentration range of 10-50 mg/L and temperature range of 20–40˚C. In batch experiments, maximum adsorption capacity of 28.7 mg/g and removal efficiency of 93% were obtained. Adsorption equilibrium data were well-fitted with ...

In this study, tea waste (TW) is employed for the removal of Congo red (CR) from aqueous solutions in a fixed-bed column at 30 °C. The breakthrough curves of the adsorption process of CR on TW at three different flow rates are determined. The results revealed that the breakthrough curves were dependent on flow rates in a manner in which a lower flow rate was in favor of the CR adsorption in the...

the dynamics of multicomponent adsorption in a fixed bed adsorber is examined numerically. the dynamic model of adsorption in the packed column included axial dispersion and variable space velocity along the bed for the multicomponent adsorption adsorption the pore fluid and the solid phase are in equilibrium with a nonlinear isotherm. the numerical solution is based upon the modified lax-wendr...

In this study, bimodal meso-porous silica (UVM-7) synthesized and fabricated amino silane modified supports were characterized by powder X-ray diffraction (XRD), N2 adsorption/desorption, transmission electron microscope (TEM), elemental analysis and titration. Capacity of CO2 capture on modified bimodal pore structure silica at 70°C was calculated using breakthrough curves; and it was found th...

The sorption of thorium and uranium ions by functionalized SBA–15 mesoporous silica materials with Schiff base ligating groups N–propylsalicylaldimine (SBA/SA) and ethylenediaminepropylesalicylaldimine (SBA/EnSA) from aqueous solution was investigated in fixed-bed column method. The TEMPeffect of pH, sample solution volume, and the column design parameters such as sample and eluent flow rat...