In this paper, an upper bound approach is used to analyze the extrusion process of bimetallic rods through arbitrarily curved dies. Based on a spherical velocity field, internal, shearing and frictional power terms are calculated. The developed upper bound solution is used for calculating the extrusion force for two types of die shapes: a conical die as a linear die profile and a streamlined di...

Bimetallic nanostructured core-shell structures are commonly used as catalysts in a wide variety of reactions. We surmised that the addition of an additional metal would potentially allow catalytic tailoring with the possibility of an increase in activity. Here a tri-metallic catalytic structure, consisting of clustered catalytic Pt on the surface of a Pd shell supported on a rod shaped Au core...

Abstract Bimetallic nanostructures are interesting materials for many applications ranging from plasmonics to catalysis. However, synthesizing bimetallic nanorods with good control over composition, morphology and maintaining an anisotropic shape is challenging. Here, we have shown a reproducible approach the synthesize core-shell within stabilizing mesoporous silica shell Au core Pd metal exce...

The translating and rotating rod or disk of a conventional laser vaporization cluster source is replaced by a liquid metal target. The self-regenerating liquid surface prevents cavities from being bored into the sample by laser ablation. The laser beam strikes a near pristine surface with each pulse, resulting in signals with much better short and long term stabilities. While this approach cann...

We report on the correlation between the nanocrystal and surface alloy properties with the bimetallic composition of gold-platinum(AuPt) nanoparticles. The fundamental understanding of whether the AuPt nanocrystal core is alloyed or phasesegregated and how the surface binding properties are correlated with the nanoscale bimetallic properties is important not only for the exploitation of catalyt...

Compared with their monometallic counterparts, bimetallic nanoparticles often show enhanced catalytic activity associated with the bimetallic interface. Direct quantitation of catalytic activity at the bimetallic interface is important for understanding the enhancement mechanism, but challenging experimentally. Here using single-molecule super-resolution catalysis imaging in correlation with el...

We have explored the role of electrokinetics in the spontaneous motion of platinum-gold nanorods suspended in hydrogen peroxide (H2O2) solutions that may arise from the bimetallic electrochemical decomposition of H2O2. The electrochemical decomposition pathway was confirmed by measuring the steady-state short-circuit current between platinum and gold interdigitated microelectrodes (IMEs) in the...

This review focuses on the chemical methods used to prepare supported bimetallic heterogeneous catalysts, i.e., bimetallic nanoparticles deposited on a support. The review is limited to the preparation of gold-based bimetallic catalysts and moreover to bimetallic nanoparticles supported on powder inorganic supports, i.e., on the surface or in the porosity, and not on model supports such as sing...