the ion-pair association constant values, related to the reaction +  were determined by means of the nmr spectroscopy. the values of the thermodynamic functions of the ion pairing process were calculated on the basis of the nmr results. in addition, the association entropy was found to be dependent on the temperature. comparing the experimental data and the fuoss theory it is found that  ion-pa...

the solubility of cdf2 in the mixed solvent (water(1)+ethanol(2)) with mass fraction, w1 = 0.9,was determined by using solvent evaporating method in the presence of various concentrations(0.100, 0.200, 0.300, 0.400, 0.500, 0.600, 0.800 and 1.500 mo1.1)) of naci at 25°c. the values ofsolubility and solubility product constant of cdf2 in the mixed solvent were evaluated at zero ionicstrength upon...

the solubility of kno3 in the mixed solvent (water 85%+methanol 15%) were determined by using solvent evaporating method at different temperatures (25, 30, 40, 50, 60 ;c). in addition the equilibrium constant of ion pair formation, kip, for k+no3 – ion-pair on the basis of fuoss contact ion pair model was calculated. upon choosing the extended debye-hückel model for estimating the mean activity...

The ion-pair association constant values, related to the reaction +  were determined by means of the NMR spectroscopy. The values of the thermodynamic functions of the ion pairing process were calculated on the basis of the NMR results. In addition, the association entropy was found to be dependent on the temperature. Comparing the experimental data and the Fuoss theory it is found that  ion-pa...

The solubility of CdF2 in the mixed solvent (water(1)+ethanol(2)) with mass fraction, W1 = 0.9,was determined by using solvent evaporating method in the presence of various concentrations(0.100, 0.200, 0.300, 0.400, 0.500, 0.600, 0.800 and 1.500 mo1.1)) of NaCI at 25°C. The values ofsolubility and solubility product constant of CdF2 in the mixed solvent were evaluated at zero ionicstrength upon...

Self-association of alcohols; including ethanol, methanol, cyclopentanol and octanol in separate mixtures with inert solvents have been studied using FT-IR spectroscopy. Except for the band at 3640 cm–1 in the IR spectrum of the alcohols which is due to the monomer species, the presence of other bands in the region of stretching vibrational frequencies of OH (3100-3700 cm–1) are attributed to t...