Aromatic compounds, such as benzene and its derivatives, porphyrins, fullerenes, carbon nanotubes, and graphene, have numerous applications in biomedicine, materials science, energy science, and environmental science. Metalla-aromatics are analogues of conventional organic aromatic molecules in which one of the (hydro)carbon segments is formally replaced by an isolobal transition-metal fragment...

A limited amount of information exists regarding the relationship between the chemical form of copper and the formation of chlorinated aromatics in fly ash. To understand the effects of the various forms of copper on the formation of chlorinated aromatics in real fly ash, we determined the chemical forms of copper present in various types of real fly ash using X-ray absorption near edge structu...

Fermentative bioethanol production from pyrolytic sugars was improved via aromatics removal by liquid-liquid extraction. As solvents, the ionic liquid (IL) trihexyltetradecylphosphonium dicyanamide (P666,14[N(CN)2]) and ethyl acetate (EA) were compared. Two pyrolytic sugar solutions were created from acid-leached and untreated pinewood, with levoglucosan contents (most abundant sugar) of 29.0% ...

Introduction An aromatics complex is a combination of process units that can be used to convert petroleum naphtha and pyrolysis gasoline (pygas) into the basic petrochemical intermediates: Benzene Toluene and Xylenes (BTX). Benzene is a versatile petrochemical building block used in the production of more than 250 different products. Ethylbenzene, cumene, and cyclohexane are the most important ...

We apply a cubic-plus-association equation of state to study the asphaltene precipitation from n-alkane diluted model solutions (asphalteneþtoluene), and heavy oils and bitumens. Heavy oils and bitumens are characterized in terms of saturates, aromatics/resins, and asphaltenes; n-alkanes are treated independently. The asphaltene precipitation is modeled as liquid-liquid phase equilibrium. The s...

Thin-layer chromatography/flame ionization detection (TLC/FID) allows for the fractionation of bitumen into four fractions, namely, the saturates, the aromatics, the resins A and the resins B (SARAB). The technique is rapid and economical, but it lack reproducibility. The effect of chromarod aging on reproducibility was investigated along with that of the time between bitumen dissolution and it...

Soil isolates Pseudomonas putida CSV86, Pseudomonas aeruginosa PP4 and Pseudomonas sp. C5pp degrade naphthalene, phthalate isomers and carbaryl, respectively. Strain CSV86 displayed a diauxic growth pattern on phenylpropanoid compounds (veratraldehyde, ferulic acid, vanillin or vanillic acid) plus glucose with a distinct second lag-phase. The glucose concentration in the medium remained constan...

The behavior of the aromatic features as a function of metallic-ity/radiation field hardness in M101 HII regions and starburst galaxies is investigated using Spitzer/IRS spectra. These spectra reveal that the 6.2, 7.8+8.6, and 11.3 µm aromatics have different dependencies on metallicity/radiation field hardness. Specifically, the 6.2 and 7.8+8.6 µm aromatics are weak or absent at a metallicity,...

Citation: Averesch NJH and Krömer JO (2018) Metabolic Engineering of the Shikimate Pathway for Production of Aromatics and Derived Compounds—Present and Future Strain Construction Strategies. Front. Bioeng. Biotechnol. 6:32. doi: 10.3389/fbioe.2018.00032 metabolic engineering of the Shikimate Pathway for Production of aromatics and Derived compounds—Present and Future Strain construction Strate...