the density (d), speed of sound (u) and electrolytic conductivity (λ) for systems containing acetaminophen, ionic liquid {1-octyl-3-methyl imidazolium bromide, [omim] br} and water have been measured at t = 293.15-308.15 k. the measured data have been applied to calculate, standard partial molar volume ( ), hepler’s constant , apparent molar isentropic compressibility (kφ), transfer volume ( ),...

the physicochemical properties of solute in solutions provide valuable information on solute –solvent, solute – solute and solvent – solvent interactions. the intermolecular forces between theliquids molecules and solvent molecules affect the viscosity of the solution. information regardinginter and intra molecular interactions can be obtained from volumetric, and viscometric data in asolute so...

This paper reports density and speed of sound data for solutions of the ionic liquids (ILs) [C4mim]Cl and [C4mim][CF3SO3] in aqueous solution of 0.05 w/w amino acids of alanine, serine and proline at T = (288.15, 298.15, 308.15 and 318.15) K. From the experimental data measured, the apparent molar volume (Vϕ), isentropic compressibility ( ), and apparent molar isentropic compression ( ) have be...

Aqueous solutions of mono, di, and triprotic acids were prepared with different molar percentages (say 10%, 20% and 30%). ammonium dihydrogen phosphate is gradually introduced in the aqueous solutions at different concentrations varied from 0.1M to 0.6M at 303K. Densities, viscosities, and velocity of sound of aqueous solutions are measured and they are used to evaluate the other parameters lik...

The density (d), speed of sound (u) and electrolytic conductivity (Λ) for systems containing acetaminophen, ionic liquid {1-octyl-3-methyl imidazolium bromide, [OMIm] Br} and water have been measured at T = 293.15-308.15 K. The measured data have been applied to calculate, standard partial molar volume ( ), Hepler’s constant , apparent molar isentropic compressibility...

In this work, we report the thermodynamic and ultrasonic properties of ascorbic acid (vitamin C) in water and in presence of newly synthesized ammonium based protic ionic liquid (diethylethanolammonium propionate) as a function of concentration and temperature. Apparent molar volume and apparent molar isentropic compression, which characterize the solvation state of ascorbic acid (AA) in presen...

A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation)...

Apparent molar compressibilities (φk) and apparent molar volume (φv) of L-valine, L-leucine andL-phenylalanine in aqueous solution of KNO3 at different concentrations have been determined at the temperature 303.15K using a standard ultrasonic frequency of 2 MHz. The above parameters can be evaluated from precise density, ultrasonic velocity and time flow measurements using a specific gravity bo...

The acoustical parameters of some synthesized azomethines have been studied from ultrasonic velocity and density measurement at different concentration in methanol and dimethyl formamide at 303.15 K. The apparent adiabatic molar compressibilities and apparent molar volume were also evaluated. The results provide useful information about solute-solute and solute-solvent interactions and are of s...