The recent penetration of renewable sources in the energy system caused a transformation of the needs of the distribution system and amplified the need of energy storage systems to properly balance the electricity grid. Among electrochemical energy storage devices, all vanadium flow batteries are those of the most promising technologies due to their high efficiency, long lifetime, reliability a...

A transient modelling framework for a vanadium redox-flow battery (RFB) is developed and experiments covering a range of vanadiumconcentration and electrolyte flow rate are conducted. The two-dimensional model is based on a comprehensive description of mass, charge and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. The ...

This paper examines vanadium chloride solutions as electrolytes for an all-vanadium redox flow battery. The chloride solutions were capable of dissolving more than 2.3 M vanadium at varied valence states and remained stable at 0-50 °C. The improved stability appeared due to the formation of a vanadium dinuclear [V(2)O(3)·4H(2)O](4+) or a dinuclear-chloro complex [V(2)O(3)Cl·3H(2)O](3+) in the s...

A techno-economic model was developed to investigate the influence of components on the system costs of redox flow batteries. Sensitivity analyses were carried out based on an example of a 10 kW/120 kWh vanadium redox flow battery system, and the costs of the individual components were analyzed. Particular consideration was given to the influence of the material costs and resistances of bipolar...

A new approach for enhancing the electrochemical performance of carbon felt electrodes by employing non-precious metal oxides is designed. The outstanding electro-catalytic activity and mechanical stability of Mn(3)O(4) are advantageous in facilitating the redox reaction of vanadium ions, leading to efficient operation of a vanadium redox flow battery.

In this paper, we propose a sophisticated battery model for vanadium redox flow batteries (VRFBs), which are promising energy storage technology due to their design flexibility, low manufacturing costs on large scale, indefinite lifetime, and recyclable electrolytes. Primarily, fluid distribution is analysed using computational dynamics (CFD) considering only half-cells. Based the analysis resu...

Ž . The environmental impact of both the vanadium redox battery vanadium battery and the lead-acid battery for use in stationary applications has been evaluated using a life cycle assessment approach. In this study, the calculated environmental impact was lower for the vanadium battery than for the lead-acid one. The net energy storage efficiency of the vanadium battery was greater due to lower...

The commercial development and current economic incentives associated with energy storage using redox flow batteries (RFBs) are summarised. The analysis is focused on the all‐vanadium system, which is the most studied and widely commercialised RFB. The recent expiry of key patents relating to the electrochemistry of this battery has contributed to significant levels of commercialisation in, for...