نتایج جستجو برای: alkylmercury compounds
تعداد نتایج: 226645 فیلتر نتایج به سال:
method previously employed by westoo for the determination of alkylmercury compounds was producing very wide picks during g.c. analyses. changing the column temperature, carrier gas flow and pressure did not supersede the problem. therefore change in packing materials was experienced. 5% dc-200 on gas-chrom did not work. a packing material used for chlorinated hydrocarbons w, 80-100 mesh. as th...
Bacteria resistant to methylmercury utilize two enzymes (MerA and MerB) to degrade methylmercury to the less toxic elemental mercury. The crucial step is the cleavage of the carbon-mercury bond of methylmercury by the organomercurial lyase (MerB). In this study, we determined high resolution crystal structures of MerB in both the free (1.76-A resolution) and mercury-bound (1.64-A resolution) st...
Bacterial populations present in Hg-rich environments have evolved biological mechanisms to detoxify methylmercury and other organometallic mercury compounds. The most common resistance mechanism relies on the H(+)-assisted cleavage of the Hg-C bond of methylmercury by the organomercurial lyase MerB. Although the initial reaction steps which lead to the loss of methane from methylmercury have a...
Mercury pollution threatens the environment and human health across the globe. This neurotoxic substance is encountered in artisanal gold mining, coal combustion, oil and gas refining, waste incineration, chloralkali plant operation, metallurgy, and areas of agriculture in which mercury-rich fungicides are used. Thousands of tonnes of mercury are emitted annually through these activities. With ...
forty bacteria species commonly found in soil, sediments, and sewage effluent were exposed for acclimation to inorganic and organic mercury compounds using sterilized sediments as the culture medium. screening tests for the ability of microorganisms to methylate inorganic mercury were made on all 40 species after acclimation to 13.5 mg/i mercuric chloride. additional screening tests for demethy...
The biotransformation efficiency of alkylmercurial compounds was studied in rat liver, kidneys, blood, and brain after 2-week administration of methylmercuric chloride (MeHg) and ethylmercuric chloride (EtHg) at doses of 0.25 or 2.5 mg Hg/kg, alone or in combination with sodium selenite (Se) at a level of 0.5 mg Se/kg. Simultaneously, the level of metallothioneinlike proteins (MTP) and endogeno...
Reactivity of Cytosine with Alkylmercury Ions in the Gas Phase: the Critical Role of the Alkyl Chain
The gas-phase reactivity towards cytosine (C) of alkylmercury cations CnH2n+1Hg+, and more particularly CH3Hg+, C2H5Hg+, n-C4H9Hg+ t-C4H9Hg+, has been studied for the first time by combining tandem mass spectrometry, infrared multiple photon dissociation spectroscopy (IRMPD) density functional theory (DFT) calculations. Under electrospray conditions, interaction C with derived from chloride com...
نمودار تعداد نتایج جستجو در هر سال
با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید