Purpose: Alkyd resins constitute a very high proportion of conventional binders used in surface coatings. In order to enhance the quality of these alkyd resins methyl esters of rubber seed oil (MERSO) were used in the preparation of the resins. Methods: MERSO were obtained by in-situ alcoholysis of rubber seed. Alkyd resins having oil lengths of 45, 50 and 55% were prepared with MERSO, phthalic...

Hybrids made from an alkyd resin and an acrylic copolymer can potentially combine the desired properties of each component. Alkyd/acrylic hybrid latex particles were synthesized via miniemulsion polymerization and used to create films at room temperature. Comparisons of the alkyd auto-oxidative cross-linking rates and the associated network development are made between two alkyd resins (with di...

Among other uses, latexes are a successful alternative to solvent-borne binders for coatings. Efforts are made to produce hybrid nanostructured latexes containing an acrylic phase and an alkyd phase. However, after the film-forming process, the surfactant used to stabilize these latexes remains in the film, and its location can have a drastic effect on the application properties. Among the proc...

This paper reports findings of a study of a batch chemical process using simulation. A model of an alkyd resin plant is presented and used to carry out improvement studies, to evaluate changes in plant operating conditions. With the proposed changes, in the simulation studies, productivity could be improved to around ten percent. Key-Words: Monte Carlo simulation, alkyd process modeling, probab...

Acrylate–alkyd hybrid latex via miniemulsion polymerizations show promise as water-borne coating systems. However, poor homogeneity of the particles caused by the immiscibility of the alkyd in polyacrylate limits monomer conversion and film formation. To resolve this problem, the hybrid miniemulsion polymerization of acrylate in the presence of linoleic acid and sunflower seed oil was carried o...

Alkyd resin was prepared from shear butter oil (SBO) using the two step procedures; alcoholysis and polyesterification. The oil and alkyd resin were characterized and evaluated by standard methods, for their physico-chemical properties. The analysis showed that the alkyd resin based on Shea butter oil recorded average acid value of 15.2 (mgNaOH/g), iodine value (98.0 mg/g), P value 6.7, density...

ABSTRACT. Acrylated Parkia biglobosa medium oil alkyd prepared by the reaction between an acid containing acrylic copolymer and a monoglyceride followed by the addition of polyol and dibasic acid has been investigated for improved properties. The results revealed that acid functional acrylic copolymers containing maleic anhydride as a functional co-monomer can successfully be used to modify alk...

alkyd resins were prepared into four different sets by varying the percentage concentrationof the glycerol content. various properties such as the viscosity, surface drying time, solubilityand color of the alkyd resins were evaluated for the various sets. the alkyd resin with the highestglycerol content was the most viscous, brownish in color and having the highest molecularweight this is due t...

A novel bicomponent alkyd system was designed to decrease the usage of Cobalt-based drier due to its latent carcinogensis. The system was polymerized using a Cobalt-salt complex as an air-sensitive drier and an isopropylthioxanthone photoinitiator as a light-sensitive accelerator, as well as using irradiation in the form of visible light. The combined influence of the two additives on autoxidat...

Currently, the most promising approach in the corrosion protection of smart coatings is the use of nanoreservoirs loaded with corrosion inhibitors. Nanocontainers are filled with anti-corrosive agents and are embedded into a primer coating. Future prospective containers are halloysite nanotubes (HNTs) due to their low price, availability, durability, with high mechanical strength and biocompati...