oxidative coupling of methane has been studied over (mn+a+w)/sio2 catalysts in a continuous–flow microreactor, where a represents an alkali ion of li, na, k or cs having different weight percents. the main aim of this study is to find the role of alkali ions in interaction between mn and w species with sio2 to make a proper structure for catalyzing oxidative coupling of methane (ocm) reaction. ...

A method is described to obtain multicollision dissociation threshold (MCDT) values. These values provide relative reaction thresholds for dissociation in the three major gas-phase fragmentation reactions of oligosaccharides complexed to alkali metal ions. The quasimolecular ions are produced using matrix-assisted laser desorption/ionization Fourier transform mass spectrometry. The MCDTs for al...

We show that alkali metals function as effective modifiers of calcium oxalate monohydrate (COM) crystallization wherein alkali-oxalate ion parings reduce the rate of crystal growth by as much as 60%. Our findings reveal a distinct trend in alkali metal efficacy that cannot be explained by colloidal theories or simple descriptors, such as ion size, but is consistent with a theoretical model that...

INTRODUCTION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ......... 582 ALKALI-CATION SELECTIVITY IN NONLIVING SySTEMS..... . . . . . . . . . . . . . . .. 583 ALKALI-CATION SELECTIVITY IN BIOLOGICAL SYSTEMS. . . . . . . . . . . . . . . . . . .. 587 THE ORIGIN OF ALKALI-CATION EQUILIBRIUM SELECTIVITY .. .. . .. . .... . " 589 ANION SELECTIVITY. . . • . . . . . ....

Thin films of ferric ferrocyanide (Prussian Blue) were electrochemically deposited on interdigitated array (IDA) electrodes yielding systems which can be considered as chemiresistors in sensing alkali ion concentrations in an adjacent electrolyte. From the dependence of the steady-state current on the electrode (bias) potential at variable cation concentrations for different alkali ions and for...

The facile conduction of alkali ions in a crystal host is of crucial importance in rechargeable alkali-ion batteries, the dominant form of energy storage today. In this review, we provide a comprehensive survey of computational approaches to study solid-state alkali diffusion. We demonstrate how these methods have provided useful insights into the design of materials that form the main componen...

Different alkali metal atoms are observed to donate electrons to CF(3)Br molecules that are oriented in space. For collision energies high enough to overcome the Coulomb attraction, a positive ion/negative ion pair is observed and mass-analyzed using coincident time-of-flight mass spectroscopy. The alkali metal cation and various negative ions are observed. The most abundant negative ion is the...

We report a combined experimental and computational study of the whey protein β-lactoglobulin (BLG) in different electrolyte solutions. Vibrational sum-frequency generation (SFG) and ellipsometry were used to investigate the molecular structure of BLG modified air-water interfaces as a function of LiCl, NaCl, and KCl concentrations. Molecular dynamics (MD) simulations and thermodynamic integrat...

Structural optimization for heteronuclear clusters consisting of one alkali-metal ion and of up to 79 neutral rare gas atoms has been carried out. The basin-hopping Monte Carlo minimization method of Wales and Doye is used. Rare gas atoms interact with the Lennard–Jones potential, whereas the interaction between a neutral atom and an ion impurity is given by the Mason–Schamp potential. Starting...

The construction of an alkali-metal ion source is presented. It allows the acceleration of rubidium ions to an energy that enables the penetration through monolayers of graphene and hexagonal boron nitride. Rb atoms are sublimated from an alkali-metal dispenser. The ionization is obtained by surface ionization and desorption from a hot high work function surface. The ion current is easily contr...