Modification of conventional Pt/C electrocatalyst with silicomolybdic acid (SiMoA) was performed using electrochemical cyclic voltammetry method. The modified and unmodified catalysts were tested under identical conditions for electrooxidation of CO, methanol, and ethanol. In the CO-stripping experiments, the modified catalyst was characterized by significant shifts (80 and 60 mV) to lower onse...

we explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized tio2 matrix. these electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to tio2 nanotubes, respectively. titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (eg) fluoride-c...

By using Triton X-114 as structure-director and weak binding stabilizer, ultrathin Au, Pd and Pt nanowires are synthesized in seconds by reduction of inorganic metal precursors with KBH(4) in aqueous phase. The nanowires show high catalytic activity and long-term stability toward electrooxidation of alcohols.

The slow, incomplete oxidation of methanol and ethanol on platinum-based anodes as well as the high price and limited reserves of Pt has hampered the practical application of direct alcohol fuel cells. We describe the electrocatalysts consisting of one Pt monolayer (one atom thick layer) placed on extended or nanoparticle surfaces having the activity and selectivity for the oxidation of alcohol...

Nanostructured (100-x)% Pd -x % Ni (x = 1, 2, 5, 10, and 20) and (90 – y)%Pd-10%Ni-y%C (y = 0.5, 1, 2, 5, and 10) composite films are obtained on glassy carbon electrodes and characterized by XRD, TEM, cyclic voltammetry and chronoamperometric techniques for use as electrocatalysts towards methanol, ethanol, ethylene glycol and glycerol oxidations in 1 M KOH at 25°C. Results show that addition ...

Abstract Recently alcohol fuel cells has been increased consideration because of their environmental friendliness, high energy conversion efficiency and low emissions. Many effort have been made to improve the electro-oxidation performance of alcohols such as methanol, ethanol and propanol. In this work, a new method for ethanol oxidation based on core–shell titanium dioxide / carbon nanofib...

The electrochemical oxidation of 3,7-dimethylxanthine has been studied in the pH range 2.1–10.7 at pyrolytic graphite, platinum and glassy carbon electrodes. The electrooxidation of 3,7-dimethylxanthine at solid electrodes proceeds in a single 4e, 4H+ pH dependent step to give a diimine species which decomposes in chemical followup steps. The UV absorbing intermediate generated during electroox...