Electron donor–acceptor (EDA) complexes are characterized by charge-transfer (CT) processes between electron-rich and electron-poor counterparts, typically resulting in a new absorption band at higher wavelength. In this paper, we report series of novel 2,6-di(imino)pyridine ligands with different aromatic substituents their 1:2 (metal/ligand) zinc(II) which the formation CT species is promoted...

hypohidrotic ectodermal dysplasia (hed) is a rare congenital disorder arising from deficient development of ectoderm-derived structures including skin, nails, glands and teeth. the phenotype of hed is associated with mutation in eda, edar, edaradd and nemo genes, all of them disruptingnf-κb signaling cascade necessary for initiation, formation and differentiation in the embryo and adult. here w...

A large effort is being made to develop nanosorbents with tunable surface chemistry for enhanced adsorption affinity and selectivity toward target organic contaminants. Heteroatom N-doped multiwall carbon nanotubes (N-MCNT) were synthesized by chemical vapor deposition of pyridine and were further investigated for the adsorptive removal of several aromatic chemicals varying in electronic donor ...

In this work, the tuneability of the π acceptor or donor properties of a set of N-heterocyclic carbenes (NHCs) with a wide spectrum of electronic characteristics is established by means of density functional theory and energy decomposition analysis (EDA) tools. Even though the main orbital interaction contribution to the NHC coordination is the σ donation, a significant contribution of the π in...

Hypohidrotic ectodermal dysplasia (HED) is a rare congenital disorder arising from deficient development of ectoderm-derived structures including skin, nails, glands and teeth. The phenotype of HED is associated with mutation in EDA, EDAR, EDARADD and NEMO genes, all of them disruptingNF-κB signaling cascade necessary for initiation, formation and differentiation in the embryo and adult. ...

The amino alcohol meglumine solubilizes organic compounds in water and enforces the formation of electron donor acceptor (EDA) complexes haloarenes with indoles, anilines, anisoles or thiols, which are not observed solvents. UV-A photoinduced transfer within EDA induces mesolytic cleavage halide ion radical recombination arenes leading, after rearomatization proton loss to C?C C?S coupling prod...

The spectral (both absorption and fluorescence) and photoelectrochemical studies of some anionic xanthene dyes namely erythrosine B, rose bengal and eosin have been carried out in micellar solution of cationic cetyl trimethyl ammonium bromide (CTAB), anionic sodium dodecyl sulphate (SDS) and neutral triton X-100 (TX-100). The results show that all these dyes form 1:1 electron-donor-acceptor (ED...

Insights from the molecular-level mechanism of sorption of organophosphate esters (OPEs) on carbon nanotubes (CNTs) can further our understanding of the fate and transport of OPEs in the environment. The motivation for our study was to explore the sorption process of OPEs on multi-walled CNTs (MWCNTs), single-walled CNTs (SWCNTs) and their oxidized counterparts (O-MWCNTs and O-SWCNTs), and its ...

Electron donor-acceptor or EDA complexes are common precursors leading to a variety of organic and organometallic reactions, as indicated by the ubiquitous appearance of characteristic charge-transfer absorption bands. Structural effects of HOMO-LUMO interactions extant in donor-acceptor pairs, established by X-ray crystallography, are critical to the charge-tranfer excitation of various types ...

The sugar alcohol meglumine enhances the solubility of organic compounds in water and enforces formation electron donor–acceptor (EDA) complexes, enabling photochemical C−C C−S cross-coupling transformations without sensitizers. light-driven redox-neutral protocol connects haloarenes with indoles, anilines, anisoles, thiols, as reported by Burkhard König co-workers their Research Article (e2022...