نتایج جستجو برای: ring inversion

تعداد نتایج: 164449  

Journal: :Acta crystallographica. Section C, Structural chemistry 2014
Alba Montoya Braulio Insuasty Justo Cobo Christopher Glidewell

In the title compound, C26H20ClNO3, the quinoline fragment is nearly orthogonal to the adjacent aryl ring, while the rest of the molecular skeleton is close to being planar. The crystal structure contains no hydrogen bonds of any sort, but there are two π-π stacking interactions present. One, involving the quinoline ring, links molecules related by inversion, while the other, involving the two ...

2008
N. Anuradha A. Thiruvalluvar M. Mahalinga R. J. Butcher

In the title mol-ecule, C(16)H(13)Cl(2)FN(2)OS, the dihedral angle between the thio-phene and benzene rings is 80.34 (12)°. The pyrazoline ring is in an envelope conformation, and the plane through the four coplanar atoms makes dihedral angles of 85.13 (9) and 6.89 (10)° with the thio-phene and benzene rings, respectively. The C and O atoms of the acetyl group are nearly coplanar with the attac...

2012
Shumaila Younas Mughal Islam Ullah Khan William T. A. Harrison Muneeb Hayat Khan Muhammad Nadeem Arshad

In the title compound, C(13)H(11)Cl(2)NO(2)S, the dihedral angle between the aromatic rings is 76.62 (10)° and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle = -51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops.

2012
Ming-Jen Chang Hsing-Yang Tsai Tzu-Chien Fang Ming-Hui Luo Kew-Yu Chen

In the title compound, C(17)H(14)N(2)O(2), the asymmetric unit comprises two mol-ecules that are comformationally similar [the dihedral angles between the phenyl rings in each are 46.35 (2) and 48.04 (3)°], with the conformation stabilized by intra-molecular O-H⋯N hydrogen bonds, which generate S(7) rings. In the crystal, inversion-related mol-ecules are linked by pairs of weak C-H⋯O hydrogen b...

2009
Zhi Zhang Yu-Jie Li Xue-Mei Gao

In the crystal structure of the title compound, C(12)H(11)NO(2), inversion-related mol-ecules are linked into dimers by pairs of O-H⋯N hydrogen bonds between the hydr-oxy group and the pyridyl ring. In addition, a π-π inter-action [with a centroid-centroid distance of 3.78 (1) Å] is found between the two pyridyl rings of the dimer. The benzene ring forms a dihedral angle of 71.6 (1)° with the p...

2012
Li Zhao Xu-Tao Dong Si-Jia Xing Qian Cheng Ji-Xing Zhao

In the title compound, C(17)H(18)N(2)O(3), the benzene rings form a dihedral angle of 3.34 (2)°. There is a strong intra-molecular O-H⋯N hydrogen bonds (which induces planarity of the structure). In the crystal, mol-ecules are linked by pairs of O-H⋯N hydrogen bonds, forming inversion dimers.

2009
Emily M. Harcourt Daniel E. Lynch Darren G. Hamilton

The planar [maximum deviation 0.0066 (4) Å] symmetrical mol-ecule of the title compound, C(10)H(6)S(2), lies across a crystallographic inversion centre. The thio-phene rings are rotationally disordered about the acetyl-ene bond, with the two pseudo inversion-related S atoms in 0.80:0.20 occupancy sites. The C C bond distance is 1.195 (9) Å.

2014
Hong Dae Choi Pil Ja Seo Uk Lee

In the title compound, C17H15FO3S, the dihedral angle between the mean planes of the benzo-furan and 2-fluoro-phenyl rings is 87.61 (4) Å. In the crystal, mol-ecules are linked via pairs of C-H⋯π inter-actions into inversion-related dimers. These dimers are linked by C-H⋯O hydrogen bonds into supra-molecular chains running along the a-axis direction.

2011
Zhe-Rong Liu Xiao-Jing Tan De-Jian Wang Yan Wang

In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho-rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra-molecular Si-N donor-acceptor bond. In the crystal, centrosymmetrically related mol-ecules are linked by pairs of N-H⋯O hydrogen bonds into inversion dimers, generating rings with graph-set motif R(2) (2)(8)....

2013
Zeenat Fatima Thothadri Srinivasan Suman Koorathota Sathiah Thennarasu Devadasan Velmurugan

In the title compound, C16H16Cl2N4, the imidazole ring mean plane makes a dihedral angle of 70.01 (1)° with the phenyl ring. The Cl atoms deviate by -0.0472 (6) and 0.0245 (8) Å from the plane of their attached benzene ring. In the crystal, mol-ecules are linked via pairs of C-H⋯N hydrogen bonds, forming inversion dimers.

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