We report the syntheses, X-ray structures, and reductive electrochemistry of the Fe(II) complexes [(dmgBF(2))(2)Fe(MeCN)(2)] (1; dmg = dimethylglyoxime, MeCN = acetonitrile) and [(dmgBF(2))Fe((t)Bu(i)NC)(2)] (2; (t)Bu(i)NC = tert-butylisocyanide). The reaction of 1 with Na/Hg amalgam led to isolation and the X-ray structure of [(dmgBF(2))(2)Fe(glyIm)] (3; glyIm = glyimine), wherein the (dmgBF(2...

Ni(II)-dimethylglyoxime ion-imprinted polymer (Ni(II)-DMG IIP) was encapsulated in polysulphone and electrospun into nanofibres with diameters ranging from 406 to 854 nm. The structures of the Ni(II)-DMG encapsulated-IIP nanofibre, non-imprinted encapsulated-polymer nanofibre and polysulphone nanofibre mats were observed by scanning electron microscopy and evaluated by infrared spectroscopy. El...

The condensation reaction between dimethylglyoxime, acetic acid, and 4-aminophenol was significantly influenced by the [LH2] type donor derivative ligand. conducted in methanol for 24 hours while being stirred refluxed. syntheses forming a new (2E,3E)-butane-2,3-dione O2-((E)-1-((4-hydroxyphenyl)imino)ethyl) O3-((Z)-1-((4-hydroxyphenyl)imino)ethyl) dioxime) dioxime ligand [LH2]. Spectroscopic t...