Rotaxane-structure-specific Pd-catalyzed rearrangement of propargyl or allyl urethane groups to oxazolidinone moieties proceeded efficiently. The conversion took place successively by the translation of the wheel along the axle, thus providing a novel macrocyclic catalytic system.

This communication reports a novel sandwich-like rotaxane shuttle, which exhibits a unique mode of potential-controlled behaviour. Two dynamic processes occur simultaneously - conformational "unfolding" of the DADA stack accompanies translocation of the ring over the rotaxane's axle.

The synthesis of a water soluble [2]rotaxane is reported using hydrophilic secondary rim functionalised permethylated β-cyclodextrin derivatives as the axle stopper groups. The rotaxane recognises halide anions in pure water with impressive selectivity over sulfate.

The potential for lightweighting of railway axles was investigated to primarily reduce the unsprung mass a rail vehicle. reduction equates an overall lighter train which will help track damage, energy consumption and total operating costs. This work performed within NEXTGEAR project is ascribed under Shift2Rail program. paper focusses on design composite axle as part “Wheelset future” Work Pack...

This paper provides a hierarchical control strategy for cooperative braking system of an electric vehicle with separated driven axles. Two layers are defined: the top layer is used to optimize the braking stability based on two sliding mode control strategies, namely, the interaxle control mode and signal-axle control strategies; the interaxle control strategy generates the ideal braking force ...

This paper presents a method for using a dual roadside seismic sensor to detect moving vehicles on roadway by installing them on a road shoulder. Seismic signals are split into fixed time intervals in recording. In each interval, the time delay of arrival (TDOA) is estimated using a generalized cross-correlation approach with phase transform (GCC-PHAT). Various kinds of vehicle characterization...

One common mobile robot design consists of three ‘omniwheels’ arranged at the vertices of an equilateral triangle, with wheel axles aligned with the rays from the center of the triangle to each wheel. Omniwheels, like standard wheels, are driven by the motors in a direction perpendicular to the wheel axle, but unlike standard wheels, can slip in a direction parallel to the axle. Unlike a steere...

The synthesis of a peptide-containing lasso molecular switch by a self-entanglement strategy is described. The interlocked rotaxane molecular machine consists of a benzometaphenylene[25]crown-8 (BMP25C8) macrocycle surrounding a molecular axle. This molecular axle contains a tripeptidic sequence and two molecular stations: a N-benzyltriazolium and a pH-sensitive anilinium station. The tripeptid...

Usually, vehicles driven under diierent road conditions are subjected to various forces and moments. An uneven input force originating from road surface could be one of the major load aaecting ride comfort or body vibration. In order to investigate the ride and handling characteristics of a tandem axle truck, a three dimensional mathematical model is developed, and the equations of motion for t...