نتایج جستجو برای: organo

تعداد نتایج: 1783  

Journal: :Journal of the American Chemical Society 2014
Tao Yang Dorian S N Parker Beni B Dangi Ralf I Kaiser Domenico Stranges Yuan-Hsiang Su Si-Ying Chen Agnes H H Chang Alexander M Mebel

As a member of the organo sulfidoboron (RBS) family, the hitherto elusive ethynylsulfidoboron molecule (HCCBS) has been formed via the bimolecular reaction of the boron monosulfide radical (BS) with acetylene (C2H2) under single collision conditions in the gas phase, exploiting the crossed molecular beams technique. The reaction mechanism follows indirect dynamics via a barrierless addition of ...

Journal: :Inorganic chemistry 2007
Michael W Hull Slavi C Sevov

Organo-Zintl cluster ions were synthesized by reactions of alkynes with Ge94- clusters in ethylenediamine. The triple bonds are hydrogenated to double bonds during the process. The resulting dial-kenylated species [RHC=CHGe9CH=CHR]2- have lower charge, their alkali-metal cations can be exchanged for tetralkylammonium cations, and the resulting compounds are soluble in nonpolar solvents. This wa...

Journal: :Dalton transactions 2011
Carolin Albrecht Maren Bode Janaina Marinas Pérez Jörg Daniels Gregor Schnakenburg Rainer Streubel

Synthesis of the first oxaphosphirane chromium(0) and molybdenum(0) complexes of the type [{(R(1)PCH(R(2))-O}M(CO)(5)] (R(1) = C(5)Me(5)) (8a-e, 15a-e) and (R(1) = CH(SiMe(3))(2)) (9a-e, 16a-e) via reaction of dichloro(organo)- (1, 2, 10, 11) and chloro(organo)phosphane complexes (3,4,12) with lithium bases and aldehydes 7a-e is reported. Furthermore, bicyclic 1,3-oxaphospholane complexes 17 an...

2014
Cordula Vogel Carsten W. Mueller Carmen Höschen Franz Buegger Katja Heister Stefanie Schulz Michael Schloter Ingrid Kögel-Knabner

The sequestration of carbon and nitrogen by clay-sized particles in soils is well established, and clay content or mineral surface area has been used to estimate the sequestration potential of soils. Here, via incubation of a sieved (<2 mm) topsoil with labelled litter, we find that only some of the clay-sized surfaces bind organic matter (OM). Surprisingly, <19% of the visible mineral areas sh...

2012
Helmut Martin Hügel

Fluorine is the 13th most abundant element and, with other fluorine containing functional groups, is a most effective element in biological substances, pharmaceuticals, agrochemicals, liquid crystals, dyes, polymers and a wide range of consumer products. This reflects its resistance to metabolic change due to the strength of the C-F bond providing biological stability and the application of its...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی امیرکبیر(پلی تکنیک تهران) - دانشکده مهندسی پلیمر 1386

در پروژه حاضر هدف بررسی اثر تعدادی از عوامل تأثیرگذار بر ریزساختار نانوکامپوزیت‏های پلی‏اتیلن سنگین / organo-clay بود. روش خوراک‏ دهی، نوع سازگار کننده (pegma, ppgma, eva, sebsgma)، نوع مخلوط کن (مخلوط کن داخلی و اکسترودر دوپیچه) و ویسکوزیته ماتریس پلی‏اتیلنی از جمله عوامل مورد بررسی بودند. مشاهده گردید که نوع سازگار کننده هم بر درجه اینترکلیشن مذاب و هم بر ریزساختار نانوکامپوزیت‏ها تأثیر می‏گ...

Journal: :Beilstein Journal of Organic Chemistry 2021

Journal: :The Science of Nature 1960

2017
Nadia O. Ilchenko Martin Hedberg Kálmán J. Szabó

Fluorinated organic compounds have found broad application in the pharmaceutical, and agrochemical industries as well as in medical diagnostics. The impetus for the application of organouorine compounds in agrochemical and pharmaceutical products is their benecial pharmacokinetic properties, such as high metabolic stability and lipophilicity. The useful radionuclear properties of the unnatura...

Journal: :Archives of biochemistry and biophysics 2000
J M Messmore R T Raines

Pentavalent organo-vanadates have been used extensively to mimic the transition state of phosphoryl group transfer reactions. Here, decavanadate (V(10)O(28)6-) is shown to be an inhibitor of catalysis by bovine pancreatic ribonuclease A (RNase A). Isothermal titration calorimetry shows that the Kd for the RNase A decavanadate complex is 1.4 microM. This value is consistent with kinetic measurem...

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