We performed intrinsic peptide fluorescence experiments to characterize the interaction between variants of the HIV-1 Tat(32-72) peptide BP1 and TAR RNA. Kd values for wild-type BP1 and cysteine-modified BP1 were found to be in the range of 60 to 70 nM for both peptides, indicating that free sulfhydryl groups of the cysteines within the peptide are not required for high affinity TAR binding. Th...

Pyrolysis is a versatile technology for exploiting diversified feedstocks to produce wide range of products, including biochar, bio-oil, and syngas with high potential in diverse applications. The cardinal motivation pyrolysis research productively use biomass reduce adverse impacts on ecology enhance process economics. However, complex reactions pose operational challenges. Thus, the present r...

Tar bitumens are increasingly being used as a binder in road works. They consist of a standard product of about 70% bitumen and 25-30% tar. Tar bitumens are classifiable as the pyrolysis products of organic materials and are applied hot. Depending on the temperature used there are emissions of various intensities of polycyclic aromatic hydrocarbons (PAH), some of which are carcinogenic. A total...

In this contribution, high ortho novolac resins modified with phenylboronic acid were synthesized. The thermal stability of novolac resins cured with hexamethylenetetramine (HMTA) and chemical states of B and N via a pyrolysis process were studied. For the cured o-novolac modified with phenylboronic acid, the temperature with maximum decomposition rate increased by 43.5 ̋C, and the char yield i...

Tar and char can be regarded as unwanted byproducts during the gasification process. In this study, three types of catalyst, i.e., biomass char (bio-char), nickel supported on biomass (Ni+bio-char), and nickel supported on bio-char (bio-char+Ni), were studied to compare the catalytic effects of different preparation methods on tar model compound removal. The structural characteristics of the th...

Abstract Gasification of biomass produces a syngas containing trace amounts viscous hydrocarbon tar, which causes serious problems in downstream pipelines, valves and processing equipment. This study focuses on the use tire-derived pyrolysis char for tar conversion using model compounds representative tar. The catalytic decomposition compounds, including methylnaphthalene, furfural, phenol, tol...

The inert and oxidative flash pyrolysis of High Density Poly-Ethylene (HDPE) is studied 6 up to 20 000 K.s, under pressure up to 3.0 MPa and at temperature ranging from 1000 K to 7 1500 K. These conditions are considered to represent those waited onboard a hybrid rocket 8 engine using HDPE as solid fuel. Recycling applications may also find some interest. The 9 pyrolysis products are quantified...