let e be an edge of a g connecting the vertices u and v. define two sets n1 (e | g) andn2(e |g) as n1(e | g)= {xv(g) d(x,u) d(x,v)} and n2(e | g)= {xv(g) d(x,v) d(x,u) }.thenumber of elements of n1(e | g) and n2(e | g) are denoted by n1(e | g) and n2(e | g) ,respectively. the szeged index of the graph g is defined as sz(g) ( ) ( ) 1 2 n e g n e g e e    . inthis paper we compute the sz...

The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4'-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4'-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4'-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre is coordinated by four O atoms from the two dicrete oxalate ligands [Cu-O = 1.9245 (19) and 1.925...

in this paper, 4,4ʹ-bipyridinium dichloride  supported sba-15 (sba@bipy2+ 2cl-) was used for the synthesis of dihydropyrimidinones. the synthesized catalyst was characterized by ft-ir spectroscopy, scanning electron microscopy (sem), transmission electron microscopy (tem) and thermogravimetric analysis (tga). this nanocomposite was shown to be an efficient heterogeneous catalyst for the synthes...

The use of external stimuli to control the binding kinetics in supramolecular systems is critical importance for development advanced molecular machines and devices. In this work, a study focused on water-soluble host-guest system based cucurbit[8]uril two dithienylethene (DTE) photoswitches reported. It shown that DTE guest comprising anionic sulfonate side arms appended pyridinium moieties, f...

The title hydrated mol-ecular organic salt, C10H10N2 (2+)·C10H6O6S2 (2-)·2H2O, crystallized with half a bipyridinium cation, half a naphthalene-2,6-di-sulfonate anion and a water mol-ecule in the asymmetric unit. The whole cation and anion are generated by inversion symmetry, the inversion centers being at the center of the bridging C-C bond of the cation, and at the center of the fused C-C bon...

Abstract The current study presents a new class of functional derivatives ( 1–3 ) consisting dicationic viologen (4,4’-bipyridinium unit) V 2+ capped by nucleobases thymine NB 1 ), adenine 2 thymine/adenine , and ion-paired with amphiphilic anion 3,4,5-tris(dodecyloxy)benzene sulfonate DOBS − ). target our work focuses on the design synthesis molecular building blocks in which three different f...

Host-guest interactions are an attractive approach to design redox electrolytes, enabling precisely tune the key properties for flow batteries such as half-cell potential, solubility, and stability. Herein we report a host-guest complex of highly water soluble (2-hydroxypropyl)-β-cyclodextrin with 1-decyl-1′-ethyl-4,4′-bipyridinium dibromide anolyte in new aqueous organic battery (AORFB). The s...