Background: nitrogen oxides occur in the atmosphere in Six forms of namely: N2O , NO , NO2 , N2O3, N2O4 and N2O5 .Among these oxides NO2 is the most important air pollutant because of its relatively high toxicity and its ubiquity in ambient air. In this research Griess-Saltzman method was utilized for determination of nitric oxide and nitrogen dioxide in the atmosphere of different laboratori...

The electrochemical polymerization of 2-aminobenzenesulfonic acid with and without aniline has been carried by cyclic potencial sweep in sulfuric acid solution at the glassy carbon electrode. The polymer and copolymer formed have been characterized voltammetrically. The sulfonated polyaniline coated mercury thin-film electrodes have been evaluated for use with anodic stripping voltammetry. The ...

The reaction of bilirubins with aromatic diazonium salts in alcoholic solvents leads to an equimolar mixture of two types of products. One is the well-known 9-azopyrromethenone. The other is a yellow product (A,,, z 420nm) identified as 9-alkoxymethylpyrromethenone. the alkoxy-substitucnt being derived from the solvent. Thus, reaction of the symmetrically substituted bilirubins llla (lc) and XI...

Behre and Benedict (2) developed a procedure for the determination of ergothioneine, based upon the separation of this substance from uric acid, followed by estimation of the ergothioneine by its reaction with a phosphotungstic acid reagent. In discussing the inadequacies of this method and its modifications, Behre in 1932 (3) stated that “no great, reliance can be placed on the figures so far ...

Mixed anaerobic bacterial consortia have been show to reduce azo dyes and batch decolourisation tests have also demonstrated that predominantly methanogenic cultures also perform azo bond cleavage. The anaerobic treatment of wool dyeing effluents, which contain acetic acid, could thus be improved with a better knowledge of methanogenic dye degradation. Therefore, the decolourisation of two azo ...

New computational insights into the mechanism of the Boyland-Sims oxidation of arylamines with peroxydisulfate (S(2)O(8)(2-)) in an alkaline aqueous solution are presented. The key role of arylnitrenium cations, in the case of primary and secondary arylamines, and arylamine dications and immonium cations, in the case of tertiary arylamines, in the formation of corresponding o-aminoaryl sulfates...

background: nitrogen oxides occur in the atmosphere in six forms of namely: n2o , no , no2 , n2o3, n2o4 and n2o5 .among these oxides no2 is the most important air pollutant because of its relatively high toxicity and its ubiquity in ambient air. in this research griess-saltzman method was utilized for determination of nitric oxide and nitrogen dioxide in the atmosphere of different laboratories...