Over the last few decades, benefitting from the sufficient sensitivity, high specificity, nondestructive, and rapid detection capability of the surface-enhanced Raman scattering (SERS) technique, numerous nanostructures have been elaborately designed and successfully synthesized as high-performance SERS substrates, which have been extensively exploited for the identification of chemical and bio...

After its discovery more than 30 years ago, surface-enhanced Raman spectroscopy (SERS) was expected to have major impact as a sensitive analytical technique and tool for fundamental studies of surface species. Unfortunately, the lack of reliable and reproducible fabrication methods limited its applicability. In recent years, SERS has enjoyed a renaissance, and there is renewed interest in both ...

We present the results of an investigation of surface-enhanced Raman scattering (SERS) by optical phonons in colloidal CdSe nanocrystals (NCs) homogeneously deposited on both arrays of Au nanoclusters and Au dimers using the Langmuir-Blodgett technique. The coverage of the deposited NCs was less than one monolayer, as determined by transmission and scanning electron microscopy. SERS by optical ...

Preparation of surface enhanced Raman scattering (SERS) nanostructures with both high sensitivity as well as high reproducibility has always been difficult and costly for routine SERS detection. Here we demonstrate air-stable metallic glassy nanowire arrays (MGNWAs), which were prepared by a cheap and rapid die nanoimprinting technique, could exhibit high SERS enhancement factor (EF) as well as...

The detection of furfural in transformer oil through surface enhanced Raman spectroscopy (SERS) is one of the most promising online monitoring techniques in the process of transformer aging. In this work, the Raman of individual furfural molecules and SERS of furfural-Mx (M = Ag, Au, Cu) complexes are investigated through density functional theory (DFT). In the Raman spectrum of individual furf...

Surface-enhanced Raman scattering (SERS) spectroscopy has attracted tremendous interests as a highly sensitive label-free tool. The local field produced by the excitation of localized surface plasmon resonances (LSPRs) dominates the overall enhancement of SERS. Such an electromagnetic enhancement is unfortunately accompanied by a strong modification in the relative intensity of the original Ram...

Surface-enhanced Raman scattering (SERS) spectra of pyrazine and pyridine adsorbed on an “unroughened” Au(210) electrode surface have been obtained for the first time. The SERS spectra indicate that both pyridine and pyrazine adsorb on the Au(210) electrode via their nitrogen lone pairs (end-on configuration). The integrated SERS intensities from the ring-breathing vibrations (ca. 1010 cm-1 for...

For developing a free radical-quenched surface-enhanced Raman scattering (SERS) probe, starch, a linear molecule, was used as a protective layer to coat gold nanoshells (GNSs) as enhancement substrates and then, methylene blue (MB) was absorbed on the starch-coated GNSs as a free radical-responsive element. By detecting the change of the SERS intensity of MB on GNSs, the free radical-quenched S...

Since the discovery of surface-enhanced Raman spectroscopy (SERS) in 1977, scientists have come to understand the enhancement mechanism, but have been unable to consistently optimize the weak signals inherent in Raman experiments. Surface-enhanced Raman signals originate from excitation of the localized surface plasmon resonance (LSPR) of a nanostructured metal surface, thus producing concentra...