Introduction One-pot oxidation reaction consisted of direct synthesis of hydrogen peroxide (H2O2) from H2 and O2 gases and oxidation reaction using in situ generated H2O2 is promising synthetic method, because it is possible to use the unstable H2O2 immediately without isolation/purification steps, which would contribute to energy and time saving as well as avoid the risk of transportation of t...

Tyrosinase was found to catalyze the oxidation of phenylhydrazine to phenol in a reaction that did not resemble those typically performed by tyrosinase. The kinetics of this reaction was investigated by measuring the initial velocity of the formation of phenol (25 °C). The values of k cat and K M for the oxidation of phenylhydrazine were obtained as 11.0 s(-1) and 0.30 mM, respectively. The gen...

the perovskite-structured la2cuo4 nanoparticles (lco nps) have been synthesized via an ultrasonic-assisted co-precipitation route using octanoic acidas organic surfactant, and the phase composition, morphology, lattice parameters and size of nanoparticles  are characterized through fourier transform infrared spectroscopy (ft-ir), x-ray diffraction (xrd), scanning electron microscopy (sem) and t...

The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.

mercaptans are commonly present in petroleum products. their foul odor and highly corrosive nature make them the most undesirable sulfur compounds so they should be removed because of environmental issues. merox process is used for oxidation of mercaptans to disulfide using air in the presence of alkaline solution and merox catalyst. in this paper, due to lack of information about the kinetic o...

The oxidation of n-pentanol by tetramethylammonium fluorochromate in acidic solution wasstudied using spectrophotometric technique. The reaction was arranged to be under pseudo firstorderconditions respect to the oxidant. A Michaelis-Menten type kinetic was observed respect tothe substrate. The reaction is catalyzed by hydrogen ions. Dependences of the reaction rates ontemperature and different...

Ultra-thin gold nanowires (GNWs), with uniform surface crystallinity, appear much more active than gold nanoclusters in benzylic compound oxidation. Ethylbenzene oxidation was used as a model reaction and a radical chain reaction mechanism was revealed by the DFT method.

Background: High concentration of salt makes biological treatment impossible due to bacterial plasmolysis. The present research studies the process of electrochemical oxidation efficiency and optimal levels as important factors affecting pH, salt concentration, reaction time and applied voltage. Methods: The sample included graphite electrodes with specifications of 2.5 cm diameter and 15 cm he...

the aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using cu3/2[pmo12o40]/sio2 as catalyst under mild reaction condition. this reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.