نتایج جستجو برای: deuterium compounds
تعداد نتایج: 235130 فیلتر نتایج به سال:
The far-infrared powder absorption spectra, between 10 cm-’ and 350 cm-‘, of seven BEDT-TTF salts that exhibit superconductivity at or near ambient pressure, have been measured as a function of temperature, between 5 K and 300 K. The temperature dependences of the peak frequencies, along with the measured deuterium isotopic frequency shifts, separated the lattice from the internal modes. The fr...
One of the major mechanisms for terminating the actions of catecholamines and vasoactive dietary amines is oxidation by monoamine oxidase (MAO). Smokers have been shown to have reduced levels of brain MAO, leading to speculation that MAO inhibition by tobacco smoke may underlie some of the behavioral and epidemiological features of smoking. Because smoking exposes peripheral organs as well as t...
effects on chemical shift of hydrogen bonded compounds in solution. For recent more complete reviews see [7, 8, 25] and for isotope effects primarily on intermolecular hydrogen bonding and in the solid state the papers by the Limbach group [3, 4, 33, 34]. The paper will concentrate on intrinsic isotope effects and not so much on equilibrium ones. The review will also concentrate on situations w...
A rapid, sensitive, and selective method for the determination of betaines is described and discussed. The method entails derivatizing the quaternary ammonium compounds to increase their sensitivity to detection by fast atom bombardment mass spectrometry. Sensitivity of detection increases markedly as the length of the carbon chain of the alcohol used to esterify the betaine carboxylic acid gro...
the main purpose of this research was to:1.develop a coking model for thermal cracking of naphtha.2.study coke inhibition methods using different coke inhibitors.developing a coking model in naphtha cracking reactors requires a suitable model of the thermal cracking reactor based on a reliable kinetic model.to obtain reliable results all these models shall be solved simultaneously.for this pu...
The activity of the transcription factor signal transducer and activator of transcription 3 (STAT3) is dysregulated in a number of hematological and solid malignancies. Development of pharmacological STAT3 Src homology 2 (SH2) domain interaction inhibitors holds great promise for cancer therapy, and a novel class of salicylic acid-based STAT3 dimerization inhibitors that includes orally bioavai...
Development of two new techniques for studying the gas phase chemistry of negative ions is reported. Collision induced dissociation (CID) of (M-1)- ions has been accomplished in a newly constructed triple stage quadrupole mass spectrometer. This instrument was assembled by adding two additional Finnigan quadrupole mass filters to a Finnigan Model 3200 CI mass spectrometer. Generation of (M-1)- ...
introduction agates are presumed as a kind of precious stone that could be formed in magmatic, metamorphic and even sedimentary environment. mechanism for agate formation is not clear and is produced in laboratories. some hot springs and geothermal activity or white chimneys in the ocean floor, have some deposits like chalcedony but never produce agate. agate formation temperature varies betwee...
As part of an ongoing characterization of the intrinsic chemical properties of peptides, thermal hydrogen-deuterium exchange has been studied for a series of fast-atom-bombardment-generated protonated alkyldipeptides and related model compounds in the reaction with D2O, CH3OD, and ND3 in a Fourier transform ion cyclotron resonance mass spectrometer. Despite the very large basicity difference be...
Environmental factors can significantly affect disease prevalence, including neuropsychiatric disorders such as depression. The ratio of deuterium to protium in water shows substantial geographical variation, which could affect disease susceptibility. Thus the link between deuterium content of water and depression was investigated, both epidemiologically, and in a mouse model of chronic mild st...
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