Recent large-scale beetle infestations have caused extensive mortality to conifer forests resulting in alterations to dissolved organic carbon (DOC) cycling, which in turn can impact metal mobility through complexation. This study analyzed soil-water samples beneath impacted trees in concert with laboratory flow-through soil column experiments to explore possible impacts of the bark beetle infe...

A previous study involving lead(II) [Pb(II)] sorption onto ferrihydrite over a wide range of conditions highlighted the advantages of combining molecular- and macroscopic-scale investigations with surface complexation modeling to predict Pb(II) speciation and partitioning in aqueous systems. In this work, an extensive collection of new macroscopic and spectroscopic data was used to assess the a...

Stormwater runoff, a substantial source of nonpoint pollution, can be treated using Best Management Practices (BMPs), such as the Media Filter Drain (MFD). An MFD is a trench filled with an engineered media mix, usually with a grass overlay, that receives runoff from the paved roadway next to it. The MFD was shown to remove dissolved metals (zinc and copper), typical pollutants from vehicles an...

Abstract The effects of pH on nutrient availability are not solely caused by to the reaction with soils but an interaction between these and rate uptake plants. Some specific particular ions, important aspect is that plant roots soil particles both have variable charge surfaces. This influences availability, in opposite directions. Sulfate example this interplay. Its sorption decreases markedly...

The conversion of municipal sludge and poultry manure to activated carbon results in a significant ash fraction that contains several different anions and cations. The objectives of this study were to determine whether the select ions are released or leached from virgin carbon into the sorption medium at different pH values. Activated carbon was placed in solutions of pH 1, 5, or 7, and the lea...

A novel Zn(II) imprinted polymer was synthesized via a co-precipitation method using graphene oxide/magnetic chitosan nanocomposite as supporting material. The synthesized imprinted polymer was characterized by Fourier transform infrared spectrometry (FTIR) and scanning electron microscopy (SEM) and applied as a sorbent for selective magnetic solid phase extraction of zinc followed by its deter...

Zinc sorption to hydrous manganese oxide (HMO)-coated clay was investigated macroscopically, kinetically, and spectroscopically. Adsorption edges and isotherms revealed that the affinity and capacity of the HMO-coated montmorillonite was greater than that of montmorillonite, and when normalized to the oxide present, the coatings behaved similarly to the discrete Mn oxide. Over two pH conditions...

Crab shell particles were tested for its ability to remove Zn 2+ ions from aqueous solution and were evaluated in a batch reactor and in a fixed-bed column. The binding of Zn 2+ ions by crab shell was found to be affected significantly by pH, with maximum sorption capacity 71.46 mg/g observed at pH 4.5. The sorption isotherm of Zn 2+ ions on crab shell particles was modeled on the application o...

zinc ions are present in different types of industrial effluents, being responsible for environmental pollution. biosorption is a process in which solids of natural origin are employed for binding heavy metals. it is a promising alternative method to treat heavy metal wastes mainly because of high metal binding capacity. the effect of some important parameters on sorption capacity of cyanobacte...