The molecular structures of the surface overlayers of rhenium(VI1) oxide, molybdenum(V1) oxide, tungsten(V1) oxide, chromium(V1) oxide, vanadium(V) oxide, niobium(V) oxide, and titanium( IV) oxide on y-alumina were determined by in situ Raman spectroscopy under dehydrated conditions. It was found that the dehydrated surface metal oxide structures of all the systems under study, except for suppo...

Tungsten is a candidate material for ITER as well as other future magnetic fusion energy devices. Tungsten is well suited for certain hsion applications in that it has a high threshold for sputtering as well as a very high melting point. As with all materials to be used on the inside of a tokamak or similar device, there is a need to know the behavior of hydrogen isotopes embedded in the materi...

This paper focuses on the engineering procedures governing the synthesis of tungsten oxide nanocrystals and the formulation of printable dispersions for electrochromic applications. By that means, we aim to stress the relevancy of a proper design strategy that results in improved physicochemical properties of nanoparticle loaded inks. In the present study inkjet printable nanostructured tungste...

A simple chemical bath deposition method has been developed to study the formation of nanoplate morphology tungsten oxide. The obtained materials were characterized by field emission scanning electron microscopy, transmission x-ray diffractometry, Raman spectroscopy, and UV–vis diffuse reflectance spectroscopy. photocatalytic activity resulting samples was further evaluated degradation Rhodamin...

Thin amorphous films of tungsten oxide (WO3) are well known to change their optical absorption behavior upon light exposure, usually referred to as photochromic effect. Since the formation of color centers is closely related to the optical creation of electron-hole pairs the sensitivity of the photochromic effect in WO3 is limited to energies above its band-gap energy of 3.25 eV, corresponding ...

Homogenous cesium tungsten tri-oxide (CsAW1O3) and powder was prepared by solvothermal reaction using (NH4)10H2(W2O7)6 and Cs2CO3 aqueous solution followed by annealing. The cesium doped tungsten tri-oxide (CsAW1O3) nanocomposite films was deposited by the sol-gel bar-coating method onto PET-film (polyethylene terephthalate film, thickness 186 μm) substrate. The structure and sizes of ceramic p...

Amorphous Tungsten Oxide (alpha-WO3) film is one of the most studied electrochromic (EC) materials. It can be used as EC layer in EC devices. Electrochromism can be described as reversible change optical properties, by an applied external voltage. Here alpha-WO3 thin films were deposited onto glass and ITO substrates by reactive DC magnetron sputtering for EC application. Growth temperature, ox...

We demonstrate that a three dimensional (3D) crystalline tungsten trioxide (WO(3)) nanoporous network, directly grown on a transparent conductive oxide (TCO) substrate, is a suitable working electrode material for high performance electrochromic devices. This nanostructure, with achievable thicknesses of up to 2 μm, is prepared at room temperature by the electrochemical anodization of a RF-sput...

We report on the optical constants and their dispersion profiles determined from spectroscopic ellipsometry (SE) analysis of the 20%-titanium (Ti) doped of tungsten oxide (WO3) thin films grown by sputter-deposition. The Ti-doped WO3 films grown in a wide range of temperatures (25-500 °C) are amorphous and optically transparent. SE data indicates that there is no significant interdiffusion at t...