The crystal structure of Ci2HiiN2SiCl3 (monoclinic, P2i/m, Z = 2, with a: 9.284(4), b: 7.226(2), c: 10.832(5) Ä, ß = 115.14(3)°) was refined to R(F) 0.035 from 1228 independent reflections. A trigonal bipyramidal, pentacoordinate silicon is observed. The chelated complex shows two different Si-N bonds, a coordinative bond (1.984(2) A) between Si and N on the axial position and a Si-N single bon...

CC This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons. org/licenses/by-nc/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited. *Correspondence: Hee Man Kim, MD, PhD Department of Internal Medicine, Yonsei University...

The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octa-hedral (CuO(6)) environment and is coordinated by four carboxyl-ate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water mol-ecule and an ether O atom in the axial positions. In the crystal structure, weak intra- a...

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Based on the fervor and devotion of Virgin Girdle Tortosa—which gained a strong establishment from 17th century onwards—this article explores possibility cause-effect relationship between apparition in cathedral 1178 Marian appendix contained troper-proser E-TO 135 (c. 1228–1264). By comparing narration miracle sequences this appendix, we can verify existence an early incipient veneration—both ...