We have synthesized model hydrophobic silicone thin films on gold surfaces by a two-step covalent grafting procedure. An amino-functionalized gold surface reacts with monoepoxy-terminated polydimethylsiloxane (PDMS) via a click reaction, resulting in a covalently attached nanoscale thin film of PDMS, and the click chemistry synthesis route provides great selectivity, reproducibility, and stabil...

The interactions of proteins with their immobilized ligands in an electrically charged microenvironment were studied. The binding of lectins to erythrocytes and to affinity matrices was used as a model system. Lectins bind and agglutinate erythrocytes in the presence of at least 10 mM NaCl or 1 mM CaCl2, but not in deionized water. The salt dependence of the agglutination process is due to the ...

Shear strength of saturated, remolded clay mineral samples was measured in an attempt to relate strength to forces acting between clay particles. The fine fractions of the clays, purified when necessary, were consolidated to different void ratios and subjected to quick, translatory shear in a direct shear device. Relative values for shear strength were obtained in this way. Interparticle forces...

We consider the Casimir interaction between (nonmagnetic) dielectric bodies or conductors. Our main result is a proof that the Casimir force between two bodies related by reflection is always attractive, independent of the exact form of the bodies or dielectric properties. Apart from being a fundamental property of fields, the theorem and its corollaries also rule out a class of suggestions to ...

This paper extends the application of the stochastic variational method to noncentral interactions. Several examples are presented for three-and four-nucleon systems with realistic nuclear forces. The correlated Gaussians easily cope with the strong short range repulsion of the potential and the stochastic variational method efficiently selects the most important spin, isospin and orbital angul...

Geometric stochastic resonance of particles diffusing across a porous membrane subject to oscillating forces is characterized as a synchronization process. Noninteracting particle currents through a symmetric membrane pore are driven either perpendicular or parallel to the membrane, whereas, harmonic-mixing spectral current components are generated by the combined action of perpendicular and pa...

The relationship between surface charge and surface potential at the solid-liquid interface is often determined by a charge regulation process, the chemisorption of a potential determining ion such as H(+). A subtle ion-specific effect can be observed when other ions compete with the primary potential determining ion to bind to a surface site. Site competition may involve alternative ions compe...

A variational technique to describe the ground and scattering states below the break–up threshold for a three-nucleon system is developed. The method consists in expanding the wave function in terms of correlated Harmonic Hyper-spherical functions suitable to handle the large repulsion contained in the nuclear potential at short distances; three body forces have also been considered. The inclus...

Recognizing that value involves experiencing pleasure or pain is critical to understanding the psychology of value. But hedonic experience is not enough. I propose that it is also necessary to recognize that strength of engagement can contribute to experienced value through its contribution to the experience of motivational force--an experience of the intensity of the force of attraction to or ...