We have exactly enumerated all sequences and conformations of hydrophobic-polar (HP) proteins with chains of up to 19 monomers on the simple cubic lattice. For two variants of the HP model, where only two types of monomers are distinguished, we determined and statistically analyzed designing sequences, i.e., sequences that have a nondegenerate ground state. Furthermore we were interested in cha...

We show that Wang-Landau sampling, combined with suitable Monte Carlo trial moves, provides a powerful method for both the ground state search and the determination of the density of states for the hydrophobic-polar (HP) protein model and the interacting self-avoiding walk (ISAW) model for homopolymers. We obtain accurate estimates of thermodynamic quantities for HP sequences with >100 monomers...

The study of dielectric relaxation properties in the binary mixture of polar molecules has been carried out at 25oC temperature for 11 different concentrations using time domain reflectometry technique. The dielectric properties of solute-solvent mixture in the microwave frequency range of 10MHz to 30GHz gives information about the formation of monomers and multimers as well as interaction betw...

In order to increase the water content and the oxygen permeability of hydrogels used in themanufacture of contact lenses, the polar monomer Silicon Hydrogel Contact Lenses (SHCL), and 2-hydroxyethyl methacrylate (HEMA) were copolymerized with the hydrogels. Due to the presence ofpolar monomers in the conventional contact lenses, the major component of the human tear,lysozyme is extensively adso...

This mini-review focuses on recent advances on the synthesis, structure, and characterization of allyl-based rare earth organometallic complexes, with emphasis on their ability to catalyze the polymerization of non-polar monomers such as conjugated dienes, styrene, and their related copolymerization.

in order to increase the water content and the oxygen permeability of hydrogels used in themanufacture of contact lenses, the polar monomer silicon hydrogel contact lenses (shcl), and 2-hydroxyethyl methacrylate (hema) were copolymerized with the hydrogels. due to the presence ofpolar monomers in the conventional contact lenses, the major component of the human tear,lysozyme is extensively adso...

Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.

This review article describes developments in chiral metallocenes as polymerization catalysts focusing on C2 symmetric ansa-zirconocene complexes. Selective synthesis of rac-isomers of ansa-zirconocenes are surveyed. Isospecific polymerizations of propylene catalyzed by chiral zirconocenes are summarized. Advanced series of polymerizations by chiral metallocenes such as asymmetric polymerizatio...

Introducing polar functionalities to polyolefins such as polyethylene and polypropylene is highly desirable for improving physical properties of the otherwise non-polar material. The synthesis stereoregular functionalized polyolefins, however, has been a relatively underdeveloped area compared that because lack suitable catalysts tolerate groups while possessing stereoselectivity. This review s...