In this work, a new mechanism is proposed for the redox of hypophosphorous acid catalyzed by a nickel cluster through a combined study of density functional theory (DFT) calculations and electrochemical impedance spectroscopy (EIS) measurements. The DFT results indicate that the concentration of OH is a crucial species to control the oxidation and reduction of hypophosphorous acid. The oxidatio...

Ni/Au plated finishes used on thick-film metallized multilayer ceramic packages for integrated circuits must meet functional requirements such as bondability, sealability, and solderability. Their ability to do so is dependent, among other things, upon the ability of the Au deposit to inhibit the grain boundary diffusion and subsequent surface oxidation of Ni. In this study, the relationship be...

Due to the high hardness and wear resistance, electroless nickel-boron (Ni-B) coatings have found numerous applications. In the present study, the influence of the heating rate on the morphological features of oxidized electroless Ni-B coatings was investigated. The oxidation behavior of electroless coating layers was studied with TGA method under non-isothermal conditions at heating rates 5, 9...

Electroless composite coatings used for achieving of high hardness, lubrication properties, non-stick surface, abrasive coating applications that by impregnation of soft and hard particles into Ni matrix. Electroless Nickel-phosphorous coatings properties and performance is greatly affected by the amount of phosphorus in them. The phosphor in this coating usually varies from 1 to 13 percent. In...

In the present stady, thermochemical treatment in H2/NH3 atmosphere was used as a post-treatment for electroless Ni-P coatings on the AISI 4140 steel substrates. High phosphorus (9%) coatings with thicknesses of 2, 24 and 48 m were applied and the effects of the thermochemical treatment on the morphology, structural changes, roughness, hardness and wear resistance of coatings were studied b...

In the present stady, thermochemical treatment in H2/NH3 atmosphere was used as a post-treatment for electroless Ni-P coatings on the AISI 4140 steel substrates. High phosphorus (9%) coatings with thicknesses of 2, 24 and 48 m were applied and the effects of the thermochemical treatment on the morphology, structural changes, roughness, hardness &#10&#10and wear resistance of coatings were studi...

Novel nickel-based microlattice materials with structural hierarchy spanning three different length scales (nm, lm, mm) are characterized microstructurally and mechanically. These materials are produced by plating a sacrificial template obtained by self-propagating photopolymer waveguide prototyping. Ni–P films with a thickness of 120 nm to 3 lm are deposited by electroless plating, whereas thi...

Flip Chip (FC) Technology is gaining an increased level of importance for a variety of applications based on Flip Chip on Board or Flip Chip in Package. The first driving force for the introduction of this Technology was the need to achieve increased speed and performance along with higher I/O count. A breakthrough, however, will be the use of flip chip due to cost reduction. For this aim it is...

Compression springs were prepared from Cr-Si high strength spring steel and coated with pure Zn and ZnNi by electroplating process. The effect of baking after electroplating as well as applying an electroless nickel interlayer on the fatigue and fatigue corrosion of the springs was investigated. The results were analyzed using weibull statistical model. A considerable improvement (8%) in fati...