Ionic liquids (IL) and hyperbranched polymers (HyP) represent new classes of nonvolatile selective solvents. By measuring vapor-liquid equilibria (VLE) of azeotropic and close boiling systems in the presence of ionic liquids or hyperbranched polymers, separation factors are derived and the potential of using IL and HyP as entrainer for extractive distillation is discussed. Exemplarily, the supe...

Three types of commonly used commercial treatment processes were investigated for the removal of volatile organic compounds (VOCs) from hazardous waste: thin-film evaporation, steam stripping, and distillation. These Unit operations were evaluated for their potential to control emissions from hazardous waste treatment, storage and disposal facilities (TSDFs) by reducing waste VOC content. One-d...

Distillation is a physical process used to separate a fluid mixture of two (binary) or more (multicomponent) substances into its component parts. In most cases, the components to be separated are miscible liquids with different volatilities and boiling points. This separation process is a thermal unit operation that utilizes the differences of vapour pressure to produce the separa‐ tion. In thi...

The catalytic-distillation process for the production of t-amyl-methyl-ether (TAME) from methanol and isoamylenes was simulated by developing the process model as a combination of unit operations from HYSYS operations palette. Geometrical characteristics of catalytic-distillation column are those of an industrial pilot plant and the results of simulation were compared with experimental data. T...

This work presents the results from dynamic modeling and control of an azeotropic distillation system. The model was validated with experimental data from a packed distillation unit. The physically-based process dynamic model, developed in HYSYS, was linked online with the control software used in the process. Model parameters were modified online using a feedback configuration to eliminate the...

The understanding of the dynamic behavior of distillation columns has received considerable attention due to the fact that distillation is one of the ost widely used unit operations in chemical process industries. Thermally coupled distillation sequences (TCDS) can provide significant energy avings with respect to the operation of sequences based on conventional distillation columns. TCDS exhib...

Process intensification refers to technologies and strategies that enable simpler and more efficient processes compared to conventional processes. Some features of such intensified processes are less recycle streams, reduced need for waste handling and lower investment and operating costs compared to conventional processes. One way of doing this is by making two or more process steps simultaneo...