The chemistry behavior of steel electrode in acid solutions has been studied by galvano static polarization technique. The consequences of concentrations of acid and temperature of solution are examined. It was found that greater the citric acid concentration or reducing of temperature of the solution assist the passivation process. The values of icorr decreased with greater concentrations of c...

A corrosion inhibitor suitable for industrial production and field application was rapidly synthesized from benzene-1,2-diamine, benzaldehyde, methanol, hydrochloric acid, and FeCl3. The mechanism of corrosion and its inhibition was proposed. We investigated the effect of the main reactants on corrosion rate, and optimal synthetic composition (benzene-1,2-diamine 10 g, b...

Sulfur recirculation is a new technology for reducing boiler corrosion and dioxin formation. It was demonstrated in full-scale tests at a Waste to Energy plant in Göteborg (Sweden) during nearly two months of operation. Sulfur was recirculated as sulfuric acid from the flue gas cleaning back to the boiler, thus creating a sulfur loop. The new technology was evaluated by extensive measurement ca...

the electrochemical behaviour of lead electrode in hydrochloride solution containing variousoxo-anions at different concentrations was studied by using of cyclic voltammetry (cv) method.results obtained show that the addition of these inorganic compounds decreases the anodic andcathodic currents peaks according to the following order: h2po4- > hpo42-> so42-. it’s revealedalso that the cathodic ...

vanillin is an interesting corrosion inhibitor because of its safe use and high solubility inwater. the effect of vanillin on the corrosion inhibition of carbon steel in 1.0 mhydrochloric acid solution has been studied using potentiodynamic polarization,electrochemical impedance spectroscopy (eis) and electrochemical noise (en) techniques.the effect of temperature on the rate of corrosion in th...

The stability of an electrodeposited nanocrystalline Ni-based alloy coating in a H₂S/CO₂ environment was investigated by electrochemical measurements, weight loss method, and surface characterization. The results showed that both the cathodic and anodic processes of the Ni-based alloy coating were simultaneously suppressed, displaying a dramatic decrease of the corrosion current density. The co...

Precipitate-free Fe-Cr-Ni f.c.c. alloys exhibit strong intergranular corrosion in acid solutions at electrochemical potentials from the transpassivity range. Segregation of impurity atoms to grain boundaries is generally considered to be responsible for this specific kind of localized damage. A study of the influence of silicon, phosphon~s and carbon on the intergranular transpassive corrosion ...

In carbon dioxide (CO2) corrosion of steels, the bicarbonate ion (HCO3) is simultaneously the buffer for carbonic acid (H2CO3), the source of iron carbonate (FeCO3) precipitation, and the product of the cathodic reaction. In addition to spatial separation of the production of Fe2+ and HCO3, galvanic coupling between the steel and cementite (Fe3C) layers is the principal cause of internal acidif...

Oil well stimulation, usually done with hot solutions of hydrochloric acid, may induce severe corrosion attack on production tubing, downhole tools and casing. Inorganic, organic and combinations of acids along with surfactants are used in a variety of well stimulation treatments. To reduce the aggressive attack of the acid on tubing and casing materials (N80 steel), inhibitors are added to the...

The influences of glucose and amino acid (L-cysteine) on the degradation of pure magnesium have been investigated using SEM, XRD, Fourier transformed infrared (FTIR), X-ray photoelectron spectroscopy (XPS), polarization and electrochemical impedance spectroscopy and immersion tests. The results demonstrate that both amino acid and glucose inhibit the corrosion of pure magnesium in saline soluti...