The Fischer-Tropsch synthesis (FTS) has been recognized as a heterogeneous surface-catalyzed polymerization process. During this process, CHx monomers formed via the hydrogenation of adsorbed CO on transition metals produce hydrocarbons and oxygenates with a broad range of chain lengths and functional groups. A series of Fe/Cu Fischer-Tropsch synthesis catalysts incorporated with a calcium prom...

The kinetics of the transformation metallic Fe to active carbide phase at start Fischer–Tropsch (FT) reaction were studied. diffusion rates C atoms going in or out lattice determined using 13C-labeled synthesis gas combination with measurements transient 12C and 13C contents by temperature-programmed hydrogenation. In initial 20 min, diffuses rapidly into occupying thermodynamically very stable...

Cobalt-based catalysts are widely used to produce liquid fuels through the Fischer-Tropsch (FT) reaction. However, the cobalt nanocatalysts can exhibit intriguing size-dependent activity whose origin remains heavily debated. To shed light on this issue, the electronic structures of cobalt nanoparticles with size ranging from 4 to 10 nm are studied using soft X-ray absorption (XAS) and resonant ...

A continuous process involving gasification, syngas cleaning, and Fischer-Tropsch (FT) synthesis was developed to efficiently produce synthetic aviation turbine fuels (SATFs). Oak-tree wood chips were first gasified to syngas over a commercial pilot plant downdraft gasifier. The raw wood syngas contains about 47% N(2), 21% CO, 18% H(2), 12% CO(2,) 2% CH(4) and trace amounts of impurities. A pur...

The second-generation bio aviation fuel production via Chemical Looping Gasification (CLG) of biomass combined with downstream Fischer-Tropsch (FT) synthesis is a possible way to decarbonize sector. CLG process has the advantage producing undiluted syngas without use an air-separation unit (ASU) and improved yield compared conventional gasification processes. This study based on modelling full ...

Fischer-Tropsch synthesis with a commercial cobalt catalyst (Albemarle) has been carried out under various combinations of two process parameters, viz. reaction pressure and GHSV (gas hourly space velocity) using synthesis gas with molar ratio of H2/CO = 2. The optimum set of reaction parameters that yielded hydrocarbon product in the desired carbon number range of C10-C14 and chain growth prob...

Municipal solid waste (MSW), comprising food waste, residential rubbish and commercial waste, has been identified as a potential feedstock for the production of alternative fuels. Conversion of MSW to fuel could displace petroleum-derived fuels to mitigate greenhouse gas (GHG) emissions from transportation, and also avoid the GHG emissions associated with existing waste management strategies su...

Kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. This issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. The Fischer Tropsch (FT) reactions have been used as the ki...

This work presents a techno-economic analysis of novel gasification system, chemical looping (CLG), used as the primary process for biofuel production through Fischer–Tropsch synthesis (FTS). Two different gas cleaning configurations, cold-gas cleanup and hot-gas trains, are explored, along with off-gas utilization possibilities, to study their influence on economics an integrated CLG–FT plant....