The monoclinic form of trilithium dichromium(III) tris-(ortho-phosphate), Li3Cr2(PO4)3, was prepared by the reactive halide flux method. The structure of the title compound is composed of a three-dimensional anionic framework with composition ∞ (3)[Cr2(PO4)3](3-) and Li(+) ions situated in the empty channels. The rigid framework built up from CrO6 octa-hedra and PO4 tetra-hedra is the same as t...

Zinc phosphate (Zn3(PO4)2) nanoparticles were successfully prepared by precipitation method using zinc acetate and Phosphoric acid as the zinc and phosphate sources. The synthesized Zn3(PO4)2 nanoparticles were characterized by X-ray diffraction, Scanning electron microscope and Transmission electron microscope in order to confirm the phase purity and morphology of the sample. Zn3(PO4)2 nanopar...

A novel trinuclear cobalt(III) phosphate complex, {[Co(en)2]3(PO4)(HPO4)}2(H2PO4)Cl7 Æ 6H2O, has been synthesized and characterized by single crystal X-ray structure determination and NMR spectroscopy. The compound includes an unprecedented type of discrete cluster with three metal atoms bridged by two phosphate anions. The clusters are associated in chains by strong hydrogen bonds PO4 H PO4. T...

The KMg4(PO4)3:Eu(2+) phosphor was prepared by the conventional high temperature solid-state reaction. The crystal structure, luminescence and reflectance spectra, thermal stability, quantum efficiency and the application for N-UV LED were studied respectively. The phase formation and crystal structure of KMg4(PO4)3:Eu(2+) were confirmed from the powder X-ray diffraction and the Rietveld refine...

Uptake of nutrients and organic C was measured once annually between 2000 and 2002 in each of 10 streams within the water-supply source areas for New York City. Nutrients (PO4 3– and NH4 þ) and organic C (glucose and arabinose) were injected into the streams for 1 to 2 h, and uptake lengths were estimated from the longitudinal declines in downstream concentration relative to that of a conservat...

A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997 ▸). Acta Cryst. C53,1754-1756]. Its structure consists of a three-dimensional framework built up from corner-sharing PO4 and (Zn,Fe)O4 tetra-hedra. This mode of linkage forms ch...

An iron-based mixed-polyanion compound, Li9Fe3(P2O7)3(PO4)2, is introduced as a possible cathode material for Li-ion batteries. Phase-pure Li9Fe3(P2O7)3(PO4)2 is successfully prepared by a sol-gel method, and its physicochemical properties are investigated in detail. Special attention is paid on making clear the variation of the phase composition with the annealing temperature and the effect of...

Renalase is a kidney-secreted catecholamines-degrading enzyme whose expression and activity are downregulated by increased dietary phosphate. A renalase knockout (KO) mouse model was used to explore the mechanisms mediating renalase's effect on phosphate excretion. Compared with wild-type (WT) mice maintained on a regular diet, KO mice show decreased serum PO4(-) (KO = 5.3 ± 0.2 vs. WT = 6.0 ± ...

Nanomaterials are extensively studied in electrochemical energy storage and conversion systems because of their structural advantages. However, their volumetric energy density still needs improvement due to the high surface area, especially the carbon based nanocomposites. Constructing hierarchical micro-scaled materials from closely stacked subunits is proposed as an effective way to solve the...

Adsorption and desorption of phosphorus (P) and nitrogen (N) by stalk residues may influence the concentrations of P and N in runoff. A laboratory study was conducted to measure the effects of P and N constituents in solution on adsorption and desorption of P and N by corn, soybean, and wheat stalk residues. Experimental variables included type of stalk material (corn, soybean, and wheat), inor...