Recent progress in simulating the properties of interfacial water at hard hydrophobic and hydrophilic surfaces is reviewed and compared to results for the air/water interface. The authors discuss static properties such as the equilibrium contact angle, the depletion layer thickness, and the orientation of interfacial water molecules. Relations between these properties, e.g., the relation betwee...

The interaction between two associating hydrophobic particles has traditionally been explained in terms of the release of entropically frustrated hydration shell water molecules. However, this picture cannot account for the kinetics of hydrophobic association and is therefore not capable of providing a microscopic description of the hydrophobic interaction (HI). Here, Monte Carlo simulations of...

The principles obtained from studies on molecular chaperones have provided explanations for the assisted protein folding in vivo. However, the majority of proteins can fold without the assistance of the known molecular chaperones, and little attention has been paid to the potential chaperoning roles of other macromolecules. During protein biogenesis and folding, newly synthesized polypeptide ch...

In the present work, we have explored the use of the triphenylmethyl group, a commonly used protecting group for primary alcohols as a gelling structural component in the design of molecular gelators. We synthesized a small library of triphenylmethyl derivatives of simple primary alcohols and studied their gelation properties in different solvents. Gelation efficiency for some of the derivative...

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 6023 wileyonlinelibrary.com Our work is inspired by passive transport across cell membranes, which offer an intriguing example of regulating membrane permeability based on transmembrane hydrophilic/hydrophobic interactions. [ 10 ] The cell membrane has a lipid bilayer structure consisting of hydrophilic phosphate outer layers and hydrophobic hyd...

BACKGROUND AND AIMS Adhesive permeability is hindered by application of an additional layer of hydrophobic resin, which increases its concentration within the hydrophilic layer, reduces its affinity to water, and enhances its physical prop-erties. The aim of the present study was to evaluate the effect of a hydrophobic layer on the microleakage of class V composite restorations using different ...

Hydrophobins are a class of small proteins that fulfill a wide spectrum of functions in fungal growth and development. They do so by self-assembling into an amphipathic membrane at hydrophilic-hydrophobic interfaces. The SC3 hydrophobin of Schizophyllum commune is the best-studied hydrophobin. It assembles at the air-water interface into a membrane consisting of functional amyloid fibrils that ...

The hydrophobic effect is the main thermodynamic driving force in the folding of water-soluble proteins. Exclusion of nonpolar moieties from aqueous solvent results in the formation of a hydrophobic core in a protein, which has been generally considered essential for specifying and stabilizing the folded structures of proteins. Outer surface protein A (OspA) from Borrelia burgdorferi contains a...

The produced liquid water in cathode catalyst layer (CCL) has significant effect on the operation of proton exchange membrane fuel cell (PEMFC). To investigate this effect, the transport of oxygen in CCL in the presence of immiscible liquid water is studied applying a two-dimensional pore scale model. The CCL was reconstructed as an agglomerated system. To explore the wettability effects, diffe...

Iron oxide nanoparticles (magnetite (Fe3O4), hematite (Fe2O3)) have been received increasing attention in drug and gene delivery. In this work, water-base double layer functionalized iron oxide nanoparticles (DL-IONPs) were designed and prepared of a biodegradable, biocompatible carrier by co-precipitation method with high DNA loading capacity due to self-assembly of a second organic layer. The...