نتایج جستجو برای: dehydration of alcohols
تعداد نتایج: 21165385 فیلتر نتایج به سال:
The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel cascades of reactions originating from a common carbocationic manifold.
Specimens to be plastinated are often moist which necessitates the removal of tissue fluid (dehydration) before forced impregnation or plastination can be carried, out. Dehydration removes the specimen fluid (water), as well as, some fat. The tissue fluid is replaced with an organic solvent. To be a dehydrating agent, the solvent must be miscible with water and may consist of a variety of chemi...
The dehydration of alcohols is involved in many organic conversions but has to overcome high free-energy barriers in water. Here we demonstrate that hydronium ions confined in the nanopores of zeolite HBEA catalyse aqueous phase dehydration of cyclohexanol at a rate significantly higher than hydronium ions in water. This rate enhancement is not related to a shift in mechanism; for both cases, t...
Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.
Biomass has the potential to serve as a sustainable source of energy and organic carbon for our industrialized society. The focus of this Review is to present an overview of chemical catalytic transformations of biomass-derived oxygenated feedstocks (primarily sugars and sugar-alcohols) in the liquid phase to value-added chemicals and fuels, with specific examples emphasizing the development of...
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