A series of alkyl-substituted ketones are shown to activate hydrogen in the presence of B(C6F5)3, affording the corresponding borinic esters RR'CHOB(C6F5)2. The mechanism is shown to proceed via H2 activation, hydride delivery and protonation of a C6F5 group. The aliphatic aldehyde Et2CHCHO reacts with B(C6F5)3 or BPh3 to give boron enolates Et2C[double bond, length as m-dash]CH(OBAr2) (Ar = C6...

We prove a classification result for properly outer actions σ of discrete amenable groups G on strongly amenable subfactors of type II, N ⊂ M , a class of subfactors that were shown to be completely classified by their standard invariant GN,M , in ([Po7]). The result shows that the action σ is completely classified in terms of the action it induces on GN,M . As a an application of this, we obta...

in the present paper, the concepts of module (uniform) approximate amenability and contractibility of banach algebras that are modules over another banach algebra, are introduced. the general theory is developed and some hereditary properties are given. in analogy with the banach algebraic approximate amenability, it is shown that module approximate amenability and contractibility are the same ...

The ionic liquid, N,N,N,N-tetramethylguanidiniumtriflate (TMGTf) was found to be an efficient catalyst solvent for Henry reaction between nitromethane and isatin derivatives to provide 3-hydroxy-3-(nitromethyl)indolin-2-one under mild conditions. The ionic liquid amenable to successive recycling without appreciable decrease in activity. Synthesized compounds have been screened for their anti-di...

For a Banach algebra $fA$, we introduce ~$c.c(fA)$, the set of all $phiin fA^*$ such that $theta_phi:fAto fA^*$ is a completely continuous operator, where $theta_phi$ is defined by $theta_phi(a)=acdotphi$~~ for all $ain fA$. We call $fA$, a completely continuous Banach algebra if $c.c(fA)=fA^*$. We give some examples of completely continuous Banach algebras and a suffici...

BACKGROUND Philadelphia chromosome-like acute lymphoblastic leukemia (Ph-like ALL) is characterized by a gene-expression profile similar to that of BCR-ABL1-positive ALL, alterations of lymphoid transcription factor genes, and a poor outcome. The frequency and spectrum of genetic alterations in Ph-like ALL and its responsiveness to tyrosine kinase inhibition are undefined, especially in adolesc...

This work concerns the chromatographic separation of protein charge variants using pH gradients generated by step changes in buffer composition with weak base anion exchange columns. A local equilibrium model is first developed to describe pH transitions occurring in the column using buffers comprising neutral, zwitterionic or positively charged species. Model predictions, based solely on the r...

Several independent experiments suggest that cell walls of Bacillus subtilis are protonated during growth. When cells were grown in the presence of fluorescein-labeled dextran to saturate the cell walls, centrifuged, and suspended in PBS, fluorescence-activated cell sorter analyses revealed the bacteria were only poorly fluorescent. In contrast, when the bacteria were purged with N(2) to dissip...