Deuterium labeling has been shown previously to affect thermodynamic interactions at polymer surfaces, polymer/polymer heterogeneous interfaces, and in bulk (away from a surface or interface). However, the changes in polymer-polymer interactions due to deuterium labeling have not been thoroughly investigated for highly immiscible systems. It is shown here that deuterium labeling can influence p...

Absrract This paper describes research in tw'o areas: heterogeneous catalysis and molecular self-asiembly. The work in heterogeneous catalysis used the platinum-catalyzed hydrogenation of diolefin(dialkyl)platinum(ll) complexes to generate platinum surface alkyls of known structure. The structure and rcactrvity of these surface alkyls were inferred from characteristic processes occurring on the...

The three-dimensional Thomas-Fermi (TF) model is used to simulate the variation of the d+d → t + p cross-section at low impact energies, when the target deuterium nucleus is embedded in metallic or insulator environments. Comparison of the computational results to recent experiments demonstrates that even though the TF model can explain some increase in the low energy cross section for metallic...

In vivo stable isotope labeling and computer-assisted metabolic flux analysis were used to investigate the metabolic pathways in petunia (Petunia hybrida) cv Mitchell leading from Phe to benzenoid compounds, a process that requires the shortening of the side chain by a C(2) unit. Deuterium-labeled Phe ((2)H(5)-Phe) was supplied to excised petunia petals. The intracellular pools of benzenoid/phe...

GC/MS/MS techniques to quantitate mixtures of acyclic stereoisomers are explored for a set of secondary n-alkyl phenyl ethers vicinally substituted with deuterium. Examination of a set of test compounds using a commercial quadrupole ion trap instrument (GC/QIT) reveals large differences between threo and erythro diastereomers when trapped molecular ions expel neutral alkene as a result of colli...

Hydrogen/deuterium exchange coupled with high-resolution mass spectrometry has become a powerful analytical approach for structural investigations of complex organic matrices. Here we report the feasibility of the site-specific H/D exchange of non-labile hydrogens directly in the electrospray ionization (ESI) source, which was facilitated by an increase in the desolvation temperature from 200 °...